期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 7, 页码 2208-2213出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201503575
关键词
BrOnsted; Lewis bases; amines; olefins; organocatalysis; ylides
资金
- Australian Research Council [DE150100517]
- Australian Research Council [DE150100517] Funding Source: Australian Research Council
In recent decades, N-heterocyclic carbenes have become established as a prevalent family of organocatalysts. N-Heterocyclic olefins, the alkylidene derivatives of N-heterocyclic carbenes, have recently also emerged as efficient promoters for CO2 fixation and polymerization reactions. Their extraordinarily strong Lewis/BrOnsted basicity suggests great potential as a new class of organocatalysts for a broad range of reactions in synthetic chemistry.
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