期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 14, 页码 5467-5476出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405522
关键词
carbon nanaborns; liquid crystals; metallogels; organic-inorganic hybrid composites; thixotropy
资金
- J. C. Bose Fellowship of DST
- CSIR
A silver ion (Ag+)-triggered thixotropic metallo(organo)gel of p-pyridyl-appended oligo(p-phenylenevinylene) derivatives (OPVs) is reported for the first time. Solubilization of single-walled carbon nanohorns (SWCNHs) in solutions of the pure OPVs as well as in the metallogels mediated by pi-pi interactions has also been achieved. In situ fabrication of silver nanoparticles (AgNPs) in the SWCNH-doped dihybrid gel leads to the formation of a trihybrid metallogel. The mechanical strength of the metallogels could be increased step- wise in the order: freshly prepared gel
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