期刊
ORGANOMETALLICS
卷 35, 期 20, 页码 3641-3646出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.6b00702
关键词
-
资金
- DFG [SFB 858]
This study describes the structural investigation of a highly versatile ruthenium-NHC (N-heterocyclic carbene) catalyst complex, which has been established for the asymmetric hydrogenation of various aromatic compounds. A complex containing an unusual doubly deprotonated NHC ligand was isolated and identified as the precatalyst to this complex. When its subsequent reactivity was monitored, two additional precatalysts, featuring partially hydrogenated naphthyl substituents, were characterized spectroscopically. Ligand hydrogenation appears to be a key activation process en route to the active catalyst.
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