期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 35, 页码 12275-12278出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201501875
关键词
amidinyl; chromophores; near infrared; radical ions; ruthenium
资金
- State of Baden-Wurttemberg
- EU [CM1202]
- Ministry of Education of the Czech Republic [LD14129]
A new non-innocent ligand redox system, N,N'-bis(4-dimethylaminophenyl) substituted acetamidinato/acetamidinyl, has been designed and described by example of structurally and spectroscopically characterized ruthenium complexes. The hitherto unreported ligand is responsible for rather intense and narrow absorptions in the near-infrared region of the one-and two-electron oxidized forms. The spectroscopic, computational, and first structural characterization of an amidinyl radical complex adds to the list of established N-based radical ligands.
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