期刊
ORGANIC LETTERS
卷 19, 期 1, 页码 86-89出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03364
关键词
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资金
- National Natural Science Foundation of China [21302057, 21405095]
- Young Talents Joint Fund of Shandong Province [ZR2015JL005]
- CPSF [2016M590736]
- Special Funding for Postdoctoral Innovation Project of Shandong Province [201501002]
- Technology Project of General Administration of Quality Supervision, Inspection and Quarantine [2016IK202]
- Zibo Positive Additive Co., Ltd.
An efficient one-pot construction of functionalized 3-methylene-5-phenyl-1,2,3,4-tetrahydropyridine derivatives via palladium-catalyzed cyclization-Heck reaction of allenamides has been described. The 3-methylene-5-phenyl-1,2,3,4-tetrahydropyridine derivatives feature a nonconjugated diene, including one endo-enamine and one exocyclic double bond, which could be used for further transformation. Both aryl and vinyl halides performed very well under the standard conditions, delivering the corresponding products efficiently.
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