期刊
ORGANIC LETTERS
卷 18, 期 21, 页码 5612-5615出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02840
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资金
- Ministere de l'Education nationale, de l'Enseignement Superieur et de la Recherche
- Centre National de la Recherche Scientifique
- China Scholarship Council
An efficient and practical route for the preparation of highly substituted fluorenones and analogues via solvent-free ruthenium trichloride mediated [2 + 2 + 2] cycloaddition of alpha,omega-diynes and alkynes has been developed. This green chemistry approach involves a solventless and atom-economical catalytic process to generate densely functionalized fluorenones and related derivatives of high synthetic utility.
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