期刊
ORGANIC LETTERS
卷 18, 期 7, 页码 1518-1521出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00060
关键词
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资金
- Wuhan University [203273463]
- Natural Science Foundation of Hubei Province [2014CFB181]
- 111 Project of the Ministry of Education of China
- National Natural Science Foundation of China [21372179, 21432007, 20874079, 21334005]
A readily available ruthenium(II) catalyst was developed for the catalytic hydrogenation of aldehydes with a TON (turnover number) up to 340000. It can be performed without base and solvent, showing highly industrial potential. High chemoselectivity can be achieved in the presence of alkenyl and ketone groups. Further application of this protocol in glucose reduction showed good efficiency. Theoretical studies revealed that the rate-determining step is the hydrogenation step, not the carboxylate-assisted H-2 activation step.
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