期刊
ORGANIC LETTERS
卷 18, 期 16, 页码 4052-4055出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01928
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资金
- National Natural Science Foundation of China [21272148, 21472121]
- Shanghai Key Laboratory of High Temperature Superconductors [14DZ2260700]
An unusual oxidative coupling reaction of isocyanide and toluene derivatives using tetrabutylammonium iodide (TBAI) as a catalyst is disclosed. The experimental results and mechanistic study show that the isocyano group acts formally as an N1 synthon during the transformation, thus expanding the reactivity profile of isocyanide.
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