期刊
ORGANIC LETTERS
卷 18, 期 4, 页码 840-843出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00131
关键词
-
资金
- National Natural Science Foundation of China [21272148, 21472121, 21272147]
- Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Science
A novel strategy to furnish selective double insertion of isocyanides with the aid of potassium tetrachloroaurate(III) has been disclosed. This strategy provides quick access to approach a complex polycyclic skeleton in an efficient manner. Unexpected oxygen migration was also observed when the reaction was conducted at a lower temperature.
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