期刊
ORGANIC LETTERS
卷 18, 期 4, 页码 680-683出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03641
关键词
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资金
- National Natural Science Foundation of China [21202103, 2137226, 51302327]
- Natural Science Foundation of Liaoning Province of China [2014020080]
- Liaoning Province Education Administration of China [L2014386]
A unique strategy for the regiospecific synthesis of bicyclic furopyran derivatives has been developed via a gold(I)-catalyzed propargyl-Claisen rearrangement/6-endo-trig cyclization of propargyl vinyl ethers. The introduction of angle strain into the substrates significantly altered the reaction's regioselectivity. Insight into the regioselectivity of the cycloisomerization was obtained with density functional theory calculations.
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