期刊
ORGANIC LETTERS
卷 18, 期 11, 页码 2672-2675出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01116
关键词
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资金
- ACT-C from JST (Japan)
- MEXT (Japan) [15H03775, 26102004]
- Umicore
- Grants-in-Aid for Scientific Research [26102004, 15H03775] Funding Source: KAKEN
It has been established that a cationic rhodium(I)/axially chiral biaryl bisphosphine complex catalyzes the asymmetric [2 + 2 + 2] cycloaddition of alpha,omega-diynes with electron-rich and unstrained unsymmetrical 1,2-disubstituted alkenes to give chiral multicyclic compounds with good yields and ee values. Interestingly, enantioselectivity highly depends on the structures of alpha,omega-diynes used presumably due to the presence of two distinct reaction pathways.
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