期刊
ORGANIC LETTERS
卷 18, 期 12, 页码 2994-2997出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01357
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资金
- NIGMS [R01-GM-113878, R01-GM-081376]
The first cross-coupling of secondary alkyl beta-trifluoroboratoketones and -esters has been achieved through application of photoredox/nickel dual catalysis. Although the related beta-trifluoroboratoamides have been effectively cross-coupled via Pd-catalysis, the corresponding ketones and esters had proven recalcitrant prior to this report. Reactions occur under mild conditions, and a variety of functional groups and sterically and electronically diverse reaction partners are tolerated.
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