期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 15, 页码 3666-3676出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob00199h
关键词
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资金
- National Natural Science Foundation of China [21472106, 21272132]
- National Key Basic Research Program of China (973 program) [2012CB933402]
Carbon dioxide (CO2), as a waste of manufacture, is a cheap and abundant C1 source. Utilization of CO2 for synthesis of carboxylic acids has been developed. Transition-metal complexes play a key role in catalytic carboxylation reactions employing CO2. This review summarizes recent advances in copper-catalyzed carboxylation reactions using CO2. The contents are arranged based on various substrates: organometallic reagents, aryl iodides, sodium sulfinates, terminal alkynes, arenes, heteroarenes, and unsaturated substrates.
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