Recent advances in catalytic decarboxylative acylation reactions via a radical process

Photocatalyst-free hypervalent iodine reagent catalyzed decarboxylative acylarylation of acrylamides with α-oxocarboxylic acids driven by visible-light irradiation

(2016) Wangqin Ji et al.   CHEMICAL COMMUNICATIONS

Carbon–Carbon Bond Forming Reactions via Photogenerated Intermediates

(2016) Davide Ravelli et al.   CHEMICAL REVIEWS

Merging Visible-Light Photocatalysis and Palladium Catalysis for C−H Acylation of Azo- and Azoxybenzenes with α-Keto Acids

(2016) Ning Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Acylation of indoles via photoredox catalysis: a route to 3-acylindoles

(2016) Lijun Gu et al.   GREEN CHEMISTRY

Oxidative Radical Addition/Cyclization Cascade for the Construction of Carbonyl-Containing Quinoline-2,4(1H,3H)-Diones

(2016) Shi-Sheng Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Induced Alkoxyl Radical Generation Enables Selective C(sp3)–C(sp3) Bond Cleavage and Functionalizations

(2016) Kunfang Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sunlight-Driven Decarboxylative Alkynylation of α-Keto Acids with Bromoacetylenes by Hypervalent Iodine Reagent Catalysis: A Facile Approach to Ynones

(2015) Hui Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual Hypervalent Iodine(III) Reagents and Photoredox Catalysis Enable Decarboxylative Ynonylation under Mild Conditions

(2015) Hanchu Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids

(2015) Lingling Chu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives

(2015) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis of Radical Reactions: A Radical Chemistry Perspective

(2015) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-light-induced photocatalytic oxytrifluoromethylation of N-allylamides for the synthesis of CF3-containing oxazolines and benzoxazines

(2015) Qiao-Hui Deng et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed tandem cyclization of olefinic dicarbonyl compounds with benzylic Csp3–H bonds for the synthesis of dihydrofurans

(2015) Li-Na Guo et al.   CHEMICAL COMMUNICATIONS

Monofluorination of Organic Compounds: 10 Years of Innovation

(2015) Pier Alexandre Champagne et al.   CHEMICAL REVIEWS

Room-Temperature Decarboxylative Couplings of α-Oxocarboxylates with Aryl Halides by Merging Photoredox with Palladium Catalysis

(2015) Wan-Min Cheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silver-Catalyzed Double-Decarboxylative Cross-Coupling of α-Keto Acids with Cinnamic Acids in Water: A Strategy for the Preparation of Chalcones

(2015) Ning Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Decarboxylative 2-Benzoylation of Oxazoles and Thiazoles with α-Oxocarboxylic Acids

(2015) Ke Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-Facilitated Oxidative Radical Decarboxylative Cross-Coupling between α-Oxocarboxylic Acids and Acrylic Acids: An Approach to α,β-Unsaturated Carbonyls

(2015) Qing Jiang et al.   JOURNAL OF ORGANIC CHEMISTRY

Transition-Metal-Free Synthesis of Ynones via Decarboxylative Alkynylation of α-Keto Acids under Mild Conditions

(2015) Peng-Fei Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Silver-Mediated Radical Cyclization of Alkynoates and α-Keto Acids Leading to Coumarins via Cascade Double C–C Bond Formation

(2015) Kelu Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Study of Silver-Catalyzed Decarboxylative Fluorination

(2015) Niki R. Patel et al.   JOURNAL OF ORGANIC CHEMISTRY

Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis

(2015) Sandrine Ventre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-free direct decarboxylative coupling of α-keto acids with thiols: a facile access to thioesters

(2015) Kelu Yan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transition-Metal-Free Tandem Radical Thiocyanooxygenation of Olefinic Amides: A New Route to SCN-Containing Heterocycles

(2015) Hua Yang et al.   ORGANIC LETTERS

Decarboxylative 1,4-Addition of α-Oxocarboxylic Acids with Michael Acceptors Enabled by Photoredox Catalysis

(2015) Guang-Zu Wang et al.   ORGANIC LETTERS

Transition-Metal-Free Synthesis of Phenanthridinones from Biaryl-2-oxamic Acid under Radical Conditions

(2015) Ming Yuan et al.   ORGANIC LETTERS

Decarboxylative Alkynylation of α-Keto Acids and Oxamic Acids in Aqueous Media

(2015) Hua Wang et al.   ORGANIC LETTERS

Merging Photoredox with Palladium Catalysis: Decarboxylative ortho-Acylation of Acetanilides with α-Oxocarboxylic Acids under Mild Reaction Conditions

(2015) Chao Zhou et al.   ORGANIC LETTERS

Alkynylation of Tertiary Cycloalkanols via Radical C–C Bond Cleavage: A Route to Distal Alkynylated Ketones

(2015) Shun Wang et al.   ORGANIC LETTERS

Diacylation of coumarins by silver-catalyzed decarboxylative cross-coupling

(2015) Hua Wang et al.   TETRAHEDRON

Formation of C(sp2)–S bonds through decarboxylation of α-oxocarboxylic acids with disulfides or thiophenols

(2015) Guangwei Rong et al.   RSC Advances

Radical 5-exo cyclization of alkynoates with 2-oxoacetic acids for synthesis of 3-acylcoumarins

(2015) Tong Liu et al.   Organic Chemistry Frontiers

De NovoSynthesis of γ,γ-Disubstituted Butyrolactones through a Visible Light Photocatalytic Arylation-Lactonization Sequence

(2014) Wei Guo et al.   ADVANCED SYNTHESIS & CATALYSIS

Combining Photoredox and Metal Catalysis

(2014) Norbert Hoffmann   ChemCatChem

Synthesis of 6-acyl phenanthridines by oxidative radical decarboxylation–cyclization of α-oxocarboxylates and isocyanides

(2014) Jie Liu et al.   CHEMICAL COMMUNICATIONS

Silver-catalyzed decarboxylative acylfluorination of styrenes in aqueous media

(2014) Hua Wang et al.   CHEMICAL COMMUNICATIONS

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis

(2014) Matthew N. Hopkinson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silver-Catalyzed Radical Tandem Cyclization: An Approach to Direct Synthesis of 3-Acyl-4-arylquinolin-2(1H)-ones

(2014) Wen-Peng Mai et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed Acylation-Oxygenation of Terminal Alkenes for the Synthesis of Dihydrofurans Bearing a Quaternary Carbon

(2014) Leiyang Lv et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Induced Chemoselective Deboronative Alkynylation under Biomolecule-Compatible Conditions

(2014) Hanchu Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Merging photoredox with nickel catalysis: Coupling of  -carboxyl sp3-carbons with aryl halides

(2014) Z. Zuo et al.   SCIENCE

Silver-catalyzed tandem radical acylarylation of cinnamamides in aqueous media

(2014) Hua Yang et al.   RSC Advances

Oxone-mediated oxidative carbon-heteroatom bond cleavage: synthesis of benzoxazinones from benzoxazoles with α-oxocarboxylic acids

(2014) Hua Wang et al.   RSC Advances

Metal-free alkynylation of α-C–H bonds of ethers with ethynylbenziodoxolones

(2014) Ruo-Yi Zhang et al.   RSC Advances

Silver catalyzed decarboxylative acylation of pyridine-N-oxides using α-oxocarboxylic acids

(2014) Rajendran Suresh et al.   RSC Advances

Silver-catalyzed decarboxylative acylation of arylglyoxylic acids with arylboronic acids

(2014) Kai Cheng et al.   RSC Advances

Silver-Catalyzed Decarboxylative Acylarylation of Acrylamides with α-Oxocarboxylic Acids in Aqueous Media

(2013) Hua Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Decarboxylative Coupling of α- Oxocarboxylic Acids with C(sp2)H of 2-Aryloxypyridines

(2013) Jinzhong Yao et al.   ADVANCED SYNTHESIS & CATALYSIS

C sp 3F Bond Formation: A Free-Radical Approach

(2013) Mukund P. Sibi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Mediated Decarboxylation/Oxidative Amidation of α-Keto Acids with Amines under Mild Reaction Conditions Using O2

(2013) Jie Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-catalyzed decarboxylative ortho-acylation of O-methyl oximes with phenylglyoxylic acids

(2013) Zhiyong Yang et al.   CHEMICAL COMMUNICATIONS

Pd(ii)-catalyzed decarboxylative acylation of phenylacetamides with α-oxocarboxylic acids via C–H bond activation

(2013) Jihye Park et al.   CHEMICAL COMMUNICATIONS

Copper-promoted decarboxylative direct C3-acylation of N-substituted indoles with α-oxocarboxylic acids

(2013) Lin Yu et al.   CHEMICAL COMMUNICATIONS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Decarboxylative Ortho Acylation of Azobenzenes with α-Oxocarboxylic Acids

(2013) Zhong-Yuan Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Ketyl-Olefin Cyclizations Enabled by Proton-Coupled Electron Transfer

(2013) Kyle T. Tarantino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes

(2013) Basudev Sahoo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bu4NI-catalyzed decarboxylative acyloxylation of an sp3 C–H bond adjacent to a heteroatom with α-oxocarboxylic acids

(2013) Shuai Zhang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-catalyzed oxidative condensation of α-oxocarboxylic acids with formamides: synthesis of α-ketoamides

(2013) Hua Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthetic applications of photoredox catalysis with visible light

(2013) Yumeng Xi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Decarboxylative Fluorination for the Synthesis of Tri- and Difluoromethyl Arenes

(2013) Satoshi Mizuta et al.   ORGANIC LETTERS

Recent Applications of Organic Dyes as Photoredox Catalysts in Organic Synthesis

(2013) David A. Nicewicz et al.   ACS Catalysis

Photo-fluorodecarboxylation of 2-Aryloxy and 2-Aryl Carboxylic Acids

(2012) Joe C. T. Leung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual Catalysis: Combination of Photocatalytic Aerobic Oxidation and Metal Catalyzed Alkynylation Reactions-CC Bond Formation Using Visible Light

(2012) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silver-Catalyzed Decarboxylative Alkynylation of Aliphatic Carboxylic Acids in Aqueous Solution

(2012) Xuesong Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution

(2012) Feng Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Acylation of Cyclic Enamides with α-Oxocarboxylic Acids by Palladium-Catalyzed C–H Activation at Room Temperature

(2012) Hua Wang et al.   ORGANIC LETTERS

Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways

(2012) Wojciech I. Dzik et al.   Chemical Science

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

(2011) Nuria Rodríguez et al.   CHEMICAL SOCIETY REVIEWS

Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis

(2011) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Pd(II)-Catalyzed Decarboxylative Cross-Coupling of Potassium Aryltrifluoroborates with α-Oxocarboxylic Acids at Room Temperature

(2011) Mingzong Li et al.   ORGANIC LETTERS

Transition metal-catalyzed decarboxylative cross-coupling reactions

(2011) Rui Shang et al.   Science China-Chemistry

Room Temperature Palladium-Catalyzed Decarboxylativeortho-Acylation of Acetanilides with α-Oxocarboxylic Acids

(2010) Ping Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Acylation of Arenes with α-Oxocarboxylic Acids via Palladium-Catalyzed C−H Activation

(2010) Mingzong Li et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Regioselective Arylation and Vinylation of Carboxylic Acids

(2010) Tetsuya Satoh et al.   SYNTHESIS-STUTTGART

Palladium/Copper-Catalyzed Decarboxylative Cross-Coupling of Aryl Chlorides with Potassium Carboxylates

(2008) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylic Acids as Substrates in Homogeneous Catalysis

(2008) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Ketones from α-Oxocarboxylates and Aryl Bromides by Cu/Pd-Catalyzed Decarboxylative Cross-Coupling

(2008) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

(2008) D. A. Nicewicz et al.   SCIENCE