期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 3, 页码 803-807出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob02262b
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资金
- CSIR, New Delhi
- CSIR
This perspective briefly describes the conceptual manifestation of a Bronsted acid promoted Au-catalyzed cyclization of yne-tethered ynamides for the construction of novel N-heterocycles. A hetero-atom assisted intramolecular 6-endo-dig cyclization of a transient ketene N,O-acetal (a masked enol-ether of an amide), generated from an ambivalent ynamide through the attack of p-TsOH, with a Au-activated yne-motif creates dihydropyridinones and benzo[f]dihydroisoquinolones. The Au(I)-catalyzed cycloisomerization of an alkyne-tethered ketene N, N-acetal to manufacture unusual cyclobutene-fused azepine scaffolds is also highlighted.
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