Rhodium(iii)-catalyzed C–C coupling of 7-azaindoles with vinyl acetates and allyl acetates

Rhodium-Catalyzed Decarbonylative Direct Olefination of Arenes with Vinyl Carboxylic Acids

(2015) Ruiying Qiu et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(iii)-catalyzed C–H allylation of electron-deficient alkenes with allyl acetates

(2015) Chao Feng et al.   CHEMICAL COMMUNICATIONS

Oxidative Olefination of Anilides with Unactivated Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Complex Under Ambient Conditions

(2015) Yuji Takahama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mild Rh(III)-Catalyzed C7-Allylation of Indolines with Allylic Carbonates

(2015) Jihye Park et al.   JOURNAL OF ORGANIC CHEMISTRY

Expedient Synthesis of Pyrroloquinolinones by Rh-Catalyzed Annulation of N-Carbamoyl Indolines with Alkynes through a Directed C–H Functionalization/C–N Cleavage Sequence

(2015) Xiao-Fei Yang et al.   ORGANIC LETTERS

An Efficient Method for the Preparation of Styrene Derivatives via Rh(III)-Catalyzed Direct C–H Vinylation

(2015) Kate D. Otley et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Oxidative Annulation of 7-Azaindoles and Alkynes via Double C–H Activation

(2015) Shuai-Shuai Li et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Oxidative Coupling of Benzoic Acids with Geminal-Substituted Vinyl Acetates: Synthesis of 3-Substituted Isocoumarins

(2014) Mingliang Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed C–H Activation/Annulation with Vinyl Esters as an Acetylene Equivalent

(2014) Nicola J. Webb et al.   ORGANIC LETTERS

Rhodium-Catalyzed Regioselective C–H Chlorination of 7-Azaindoles Using 1,2-Dichloroethane

(2014) Guangyin Qian et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct Denitrogenative C-3-Arylation of 1H-Indoles with Arylhydrazines using Air as the Oxidant

(2013) Yongxin Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Full Functionalization of the 7-Azaindole Scaffold by Selective Metalation and Sulfoxide/Magnesium Exchange

(2013) Nadja M. Barl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzedortho Acylation of Aromatic Carboxylic Acids

(2013) Patrizia Mamone et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(I)-Catalyzed Redox-Economic Cross-Coupling of Carboxylic Acids with Arenes Directed by N-Containing Groups

(2013) Fei Pan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[3]Dendralene Synthesis: Rhodium(III)-Catalyzed Alkenyl CH Activation and Coupling Reaction with Allenyl Carbinol Carbonate

(2013) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed Direct CH Allylation of Arenes with Allyl Carbonates

(2013) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aniline mediated oxidative C–C bond cleavage of α-alkoxy aldehydes in air and a model reaction for the synthesis of α-(d)-amino acid derivatives

(2013) Bin Hu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct C-2 Arylation of 7-Azaindoles: Chemoselective Access to Multiarylated Derivatives

(2013) Prakash Kannaboina et al.   ORGANIC LETTERS

Oxidant-Free Rh(III)-Catalyzed Direct C–H Olefination of Arenes with Allyl Acetates

(2013) Chao Feng et al.   ORGANIC LETTERS

Recent advances in the synthesis and properties of 4-, 5-, 6- or 7-azaindoles

(2013) Jean-Yves Mérour et al.   TETRAHEDRON

Rhodium(III)-Catalyzed Dehydrogenative Heck Reaction of Salicylaldehydes

(2012) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

2011 FDA drug approvals

(2012) Asher Mullard   NATURE REVIEWS DRUG DISCOVERY

Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group

(2012) Bin Li et al.   ORGANIC LETTERS

Small molecule inhibitors of BRAF in clinical trials

(2011) Alfonso Zambon et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Rhodium-catalyzed direct ortho C–H olefination of phenol derivatives

(2011) Chao Feng et al.   CHEMICAL COMMUNICATIONS

Scaffold-Hopping Strategy: Synthesis and Biological Evaluation of 5,6-Fused Bicyclic Heteroaromatics To Identify Orally Bioavailable Anticancer Agents

(2011) Yen-Shih Tung et al.   JOURNAL OF MEDICINAL CHEMISTRY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Oxidative C–H Bond Alkenylations in Water: Expedient Synthesis of Annulated Lactones

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Rhodium-Catalyzed Selective Olefination of Arene Esters via C−H Bond Activation

(2011) Sae Hume Park et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Oxidative Olefination ofN-(1-Naphthyl)sulfonamides Using Activated and Unactivated Alkenes

(2011) Xuting Li et al.   ORGANIC LETTERS

Pd(II)-Catalyzed Hydroxyl-Directed C−H Olefination Enabled by Monoprotected Amino Acid Ligands

(2010) Yi Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides

(2010) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Tandem Oxidative Olefination−Michael Reactions between Aryl Carboxamides and Alkenes

(2010) Fen Wang et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Oxidative Coupling ofN-Aryl-2-aminopyridine with Alkynes and Alkenes

(2010) Jinlei Chen et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation

(2010) Andy S. Tsai et al.   ORGANIC LETTERS

Rhodium-Catalyzed Mono- and Divinylation of 1-Phenylpyrazoles and Related Compounds via Regioselective C−H Bond Cleavage

(2009) Nobuyoshi Umeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C−H Activation under External-Oxidant-Free Conditions

(2009) Junliang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Azaindole Arylation at the Azine and Azole Rings viaN-Oxide Activation

(2009) Malcolm P. Huestis et al.   ORGANIC LETTERS

Meriolins (3-(Pyrimidin-4-yl)-7-azaindoles): Synthesis, Kinase Inhibitory Activity, Cellular Effects, and Structure of a CDK2/Cyclin A/Meriolin Complex†

(2008) Aude Echalier et al.   JOURNAL OF MEDICINAL CHEMISTRY