4.6 Article

Iodine-mediated regioselective synthesis of vinyl triflones from styrenes with CF3SO2Na

期刊

ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 36, 页码 8443-8447

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob01567k

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资金

  1. National Natural Science Foundation of China [21502215, 21421002, 21332010, 21272036]
  2. National Basic Research Program of China [2012CB21600]
  3. Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20020000]
  4. Youth Innovation Promotion Association CAS [2016234]
  5. Shanghai Pujiang Program [15PJ1410300]

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An unexpected regioselective synthesis of vinyl triflones was developed. This iodine-mediated C-H triflylation of styrenes with CF3SO2Na occurred at room temperature affording various vinyl triflones, which could be used for the preparation of other CF3SO2-containing compounds.

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