期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 30, 页码 10650-10653出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201501181
关键词
carborane; cobaltabisdicarbollide; macromolecules; polyanions; polybranched
资金
- Generalitat de Catalunya [2014/SGR/149]
- Spanish Ministry of Economy and Competitiveness [CTQ2013-44670-R]
A new class of globular polybranched macromolecules that contain multiple anionic metallacarborane clusters at the o-carborane periphery is reported. The water soluble high boron rich containing molecules could be of interest for boron neutron capture therapy (BNCT) as well as for drug delivery. The reinforced electrostatic noncovalent interactions between anionic polyethylene glycol cobaltabisdicarbollide (PEG-COSAN) branches and the ammonium cation have been shown using ESI-MS.
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