期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 42, 页码 14728-14731出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502586
关键词
hybrid materials; metal-complex encoding; photochemistry; photolithography; surface chemistry
资金
- Karlsruhe Institute of Technology (KIT)
- Deutsche Forschungsgemeinschaft (DFG)
- STN program of the Helmholtz association
- Fonds der Chemischen Industrie (FCI)
A platform technology for the creation of spatially resolved surfaces encoded with a monolayer consisting of different metal complexes was developed. The concept entails the light-triggered activation of a self-assembled monolayer (SAM) of UV-labile anchors, that is, phenacylsulfides, and the subsequent cycloaddition of selected diene-functionalized metal complexes at defined areas on the surface. The synthesis and characterization of the metal complexes for the UV-light assisted anchoring on the surface and a detailed study of a short-chain oligomer model system in solution confirm the high efficiency of the photoreaction. The hybrid materials obtained by this concept can potentially be utilized for the design of highly valuable catalytic or (opto-)electronic devices.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据