4.6 Article

Perdeuterated liquid crystals for near infrared applications

期刊

OPTICAL MATERIALS
卷 60, 期 -, 页码 209-213

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.optmat.2016.06.047

关键词

Liquid crystals; Infrared; Deuterium atom; Mueller matrix; Polar decomposition

资金

  1. Defense Advanced Research Project Agency (DARPA) [N10PC200054]
  2. Military University of Technology [RMN 728/2015]
  3. Polish Ministry of Science and Higher Education the Statutory Activity of Military University of Technology [PBS-654]

向作者/读者索取更多资源

For majority of Liquid Crystalline compounds the absorption occurs at two spectral regions: ultraviolet UV (due to electronic excitations) and infrared IR (caused by molecular vibrations). Both cause the absorption which deteriorates electro-optical modulation abilities of LC. In the MWIR and LWIR regions, there are many fundamental molecular vibration bands. The most intense are the ones with high anharmonicity, which in the case of LCs corresponds to the C-H bonds, especially present in the aliphatic chains. In the NIR region, overtone molecular vibration bands derived from IR region begin to appear. In the case of C-H bond system, the first overtones are present at 1.6-1.7 mu m. To reduce NIR absorptions, perdeuterated Liquid crystal has been proposed. In this paper, we report the physical and optical properties of liquid crystals based on polarimetry measurements method. We also provide a polar decomposition of experimentally measured Mueller matrix in order to determine polarization properties of the device such as depolarization and diattenuation which cannot be obtained from absorption spectra. (C) 2016 Elsevier B.V. All rights reserved.

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