期刊
CHEMISTRY OF MATERIALS
卷 27, 期 19, 页码 6668-6674出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.5b02471
关键词
-
资金
- National Program on National High-tech R&D Program of China (863 Program) [y30102161f]
- NSFC [21271180]
- Key Technology Research Projects of Qingdao [13-4-1-10-gx]
Advanced Li-ion batteries with high rate properties are in high demand and have generated much attention in the research community. Here, we present a simple sol-gel and solid-state reaction to synthesize NASICON-structured NaSn2(PO4)(3) as anode material for lithium-ion batteries. The obtained material exhibits excellent cycling performance and high rate capacity for half cell and LiFePO4/NaSn2(PO4)(3) full cell. Cyclic voltammograms (CV) and galvanostatic intermittent titration technique (GITT) were used to analyze the kinetics and thermodynamics of the electrode. Morphology and structure evolution of the NaSn2(PO4)(3) electrode after cycling were explored by transmission electron microscopy (TEM). These results showed nanoscale Sn was uniformly dispersed in the lithium phosphate matrix during the first discharge. It is proposed that the enhanced properties are attributed to the in situ formation of the ionic conductor as protective matrices, which prevents the aggregation of nanoparticles during the cycling and provides Li+ diffusion channels in the electrode for fast electrochemical reaction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据