4.8 Article

Photoinduced Processes between Pyrene-Functionalized Silicon Nanocrystals and Carbon Allotropes

期刊

CHEMISTRY OF MATERIALS
卷 27, 期 12, 页码 4390-4397

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AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.5b01769

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资金

  1. European Commission ERC Starting Grant (PhotoSi) [278912]
  2. Robert A. Welch Foundation [F-1464]
  3. US NSF [CHE-1308813]
  4. Division Of Chemistry
  5. Direct For Mathematical & Physical Scien [1308813] Funding Source: National Science Foundation

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Two families of strongly luminescent silicon nanocrystals (SiNCs) cofunctionalized with dodecyl chains and pyrene chromophores perform as light-harvesting antennae and interact with carbon allotropes. The energy harvested in the SiNC core can thus be used to populate, for example, the lowest triplet excited state of C-60.

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