Article
Chemistry, Inorganic & Nuclear
Jan Hormann, Olga Verbitsky, Xiaoyu Zhou, Beatrice Battistella, Margarete van der Meer, Biprajit Sarkar, Cunyuan Zhao, Nora Kulak
Summary: We synthesized and characterized Cu(ii) complexes CuL1-CuL6 with cyclen-based ligands. The ligands L-1-L-6 comprise different donor sets including S and O atoms. The substitution of N donor atoms with hard donor O atoms leads to efficient oxidative nucleases, but dissociation of the complex upon reduction. We are showing that the rational combination of O and S atoms next to two nitrogen donors within the macrocycle leads to the stabilization of both redox states, resulting in the highest oxidative DNA cleavage activity within this family of cyclen-based Cu(ii) complexes.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Physical
Nimya Ann Mathews, M. R. Prathapachandra Kurup
Summary: In this study, three novel mixed ligand complexes of copper were synthesized and characterized by spectroscopy and X-ray crystallography. The complexes' interaction with CT-DNA, cleavage ability, and cytotoxicity were investigated.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Applied
Nimya Ann Mathews, M. R. Prathapachandra Kurup
Summary: This study synthesized new ternary complexes derived from multisubstituted thiosemicarbazone ligands and characterized their properties using various spectroscopic and analytical methods. The complexes showed strong interactions with DNA, cleaving DNA without external agents, and exhibited potential cytotoxicity against human breast cancer cells.
APPLIED ORGANOMETALLIC CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Salman Khursheed, Mohammad Rafiq Wani, G. G. H. A. Shadab, Sartaj Tabassum, Farukh Arjmand
Summary: Two fluorine/bromine-substituted chromone (bpy) copper (II) complexes were prepared and characterized, showing strong DNA binding and efficient DNA cleavage abilities. Anticancer screening against various cancer cell lines revealed selective cytotoxic responses, with complex 2 exhibiting higher potency. Cellular uptake studies and oxidative stress assays were also conducted to validate the induced cell death phenomenon.
INORGANICA CHIMICA ACTA
(2022)
Article
Spectroscopy
Run Cheng, Wenyan Shi, Qingyun Yuan, Ruiren Tang, Yujie Wang, Di Yang, Xin Xiao, Jianping Zeng, Jingwen Chen, Yanqing Wang
Summary: Seven isatin-thiosemicarbazone analogues with different substituents were synthesized and evaluated as inhibitors of mushroom tyrosinase. The substituent modifications affected the interactions between the inhibitors and target molecules, with the thiosemicarbazido moiety playing a predominant role in the inhibition. Theoretical calculations indicated a correlation between the electronic distribution and inhibitory potency of the compounds.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Chemistry, Inorganic & Nuclear
Yating Chen, Zhilin Ke, Lingyu Yuan, Meixiang Liang, Shuhua Zhang
Summary: We synthesized and analyzed nine unique copper(II) hydrazylpyridine salicylaldehyde and 1,10-phenanthroline complexes. It was found that these complexes exhibited higher anticancer activity and lower cytotoxicity towards normal cells compared to other substances. Specifically, Cugdupt1 and Cugdupt8 induced cell death through ATP depletion and activation of mitophagy pathways.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Carmen E. Castillo, Miguel A. Gonzalvez, Andres G. Algarra, M. Jesus Fernandez-Trujillo, Montserrat Ferrer, Manuel Martinez, Manuel G. Basallote
Summary: The reaction of [Fe-II(TSC)(2)] complexes with H2O2 resulted in the formation of diamagnetic low-spin Fe-II species capable of adding up to five oxygen atoms. These species showed activity in the oxidation of thioanisole to sulfoxide and styrene to benzaldehyde. Interestingly, other ligands and complexes also catalyzed the selective sulfoxidation of thioanisole but were ineffective in styrene oxidation. These findings suggest new directions for the development of thiosemicarbazone-based metal catalysts.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Katherine A. Morgan, Michael de Veer, Luke A. Miles, Cormac A. A. Kelderman, Catriona A. McLean, Colin L. Masters, Kevin J. Barnham, Jonathan M. White, Brett M. Paterson, Paul S. Donnelly
Summary: To develop a diagnostic method for Alzheimer's disease, two antibodies specific for amyloid-beta were modified and two compounds with pendant 1,2,4,5-tetrazine groups were labelled with copper-64. The copper-64 complexes reacted with the modified antibodies in a click reaction and crossed the blood-brain barrier in mice.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Dameng Sun, Xin Huang, Ruojun Man, Xinjie Jia, Xinluan Song, Sihan Wang, Xingyong Xue, Hongming Liu, Zhen Ma
Summary: A series of Fe(ii) complexes were synthesized using modified terpyridine ligands, and they exhibited high antiproliferation activities against human cancer cell lines with low toxicity to normal cells. The carboxyl-modified complex showed significant selectivity in killing hepatoma cancer cells. These Fe(ii) complexes have potential as anticancer drugs against hepatoma cancer.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Miguel Reina, Luis Gabriel Talavera-Contreras, Yeshenia Figueroa-DePaz, Lena Ruiz-Azuara, Luis Felipe Hernandez-Ayala
Summary: This study investigated the potential inhibition of the SARS-CoV-2 main protease (M-pro) by Casiopeinas using a computational strategy. The results showed that Casiopeinas can form stable complexes with M-pro and potentially disrupt its function by binding to the active site amino acids. Casiopeinas demonstrated more efficient disruption of the protease action compared to recognized inhibitors.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Nikolai F. Romashev, Pavel A. Abramov, Ivan Bakaev, Iakov S. Fomenko, Denis G. Samsonenko, Alexander S. Novikov, Kelvin K. H. Tong, Dohyun Ahn, Pavel Dorovatovskii, Yan Zubavichus, Aleksey A. Ryadun, Olga A. Patutina, Maxim N. Sokolov, Maria Babak, Artem L. Gushchin
Summary: A series of Pt and Pd complexes with dpp-Bian and different ligands were synthesized and characterized. The Pt(dpp-Bian) complexes showed high anticancer activity at low concentrations and exhibited selectivity towards cancer cells. These complexes induced the generation of reactive oxygen species in cancer cells and were able to intercalate into DNA.
INORGANIC CHEMISTRY
(2022)
Article
Multidisciplinary Sciences
Laila H. Abdel-Rahman, Amani A. Abdelghani, Abeer A. AlObaid, Doaa Abou El-ezz, Ismail Warad, Mohamed R. Shehata, Ehab M. Abdalla
Summary: Four new Mn(II), Fe(III), and Cr(III) complexes with two Schiff base ligands have been synthesized and characterized. The complexes showed antibacterial and anticancer activities, particularly MnL2 complex demonstrated significant efficacy. The complexes also exhibited strong binding affinities to CT-DNA and may inhibit DNA replication.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Physical
Ahmed Ezzat, Mahmoud Basseem Mohamed, Ammar M. Mahmoud, Rabie S. Farag, Abdou S. El-Tabl, Ahmed Ragab
Summary: This study describes the synthesis of a thiosemicarbazone derivative and its copper and zinc complexes, and confirms their structures through elemental analysis, spectra data, and thermogravimetric analysis. The antimicrobial activity of these complexes is demonstrated, with the zinc complex exhibiting higher activity. Molecular docking studies suggest that these complexes may act as inhibitors of DHFR and topoisomerase IV.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Inorganic & Nuclear
Fagner da Silva Moura, Ygor S. Sobrinho, Carolina Stellet, Jilder D. P. Serna, Carolina B. P. Ligiero, Mauricio I. Yoguim, Daphne S. Cukierman, Renata Diniz, Odivaldo C. Alves, Nelson H. Morgon, Aguinaldo R. de Souza, Nicolas A. Rey
Summary: Copper (II) complexes are potential alternatives to platinum drugs in cancer therapy due to their multi-target mode of action. In this study, new mononuclear and dinuclear coordination compounds of copper were synthesized and characterized. The compounds showed stability in aqueous medium and were found to bind human serum albumin (HSA) with different stoichiometries and affinities. Based on these findings and the known antiproliferative activity of copper complexes, further studies on their potential against tumor cell lines are warranted.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Nerina Shahi, Paras Nath Yadav, Upendra Chaudhary, Mohd Saad, Kuldeep Mahiya, Arif Khan, Syed Shafi, Yuba Raj Pokharel
Summary: A series of novel thiosemicarbazone derivatives containing 5-methoxy isatin were designed and synthesized. One of the synthesized compounds, MeOIstPyrd, exhibited promising anticancer activity against skin cancer cell line A431. Mechanistic studies revealed that MeOIstPyrd efficiently inhibited cell proliferation, migration, and spheroid formation by activating the mitochondrial intrinsic apoptotic pathway and restoring mutant p53 function. These findings demonstrate the potential and prospects of MeOIstPyrd in cancer therapeutics.
Article
Biochemistry & Molecular Biology
Moideen Musthafa, Ramaiah Konakanchi, Rakesh Ganguly, Chandrasekar Balachandran, Shin Aoki, Anandaram Sreekanth
Summary: A series of aroyl selenourea ligands and their Ru(II) complexes were synthesized and characterized, with the molecular structures confirmed by single XRD crystal method. The cytotoxic study revealed that complexes 1 and 2 showed promising cytotoxic activity against HeLa S3 cells, while the in vitro DNA interaction studies indicated an intercalative mode of binding in the order of 1 > 2 > 3.
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2021)
Article
Food Science & Technology
Chandrasekar Kandaswamy, Sreekanth Anandaram, S. I. Davis Presley, Ahammed T. P. Shabeer
Summary: A gas chromatography tandem mass spectrometry method was developed for simultaneous determination of 133 pesticides in Black pepper. QuEChERS sample preparation method is preferred over multistep methods. Even after the cleanup, non-volatile co-extractives stick to the liner and column, affecting the instrument performance, a dilution procedure was evaluated to overcome the drawbacks.
JOURNAL OF FOOD SCIENCE AND TECHNOLOGY-MYSORE
(2021)
Article
Chemistry, Inorganic & Nuclear
Merlin Mary Mathew, Anandaram Sreekanth
Summary: A new fluorescent probe based on Thiophene-dicarbohydrazide was synthesized for the detection of Zn2+ ions and showed highly emissive behavior upon complexation. The chemosensor exhibited a binding constant of 1.15 x 10(4) M-1 and a low detection limit of 1.51 x 10(-7) M, below the permissible level in drinking water. The fluorescent enhancement was attributed to a chelation enhanced fluorescence mechanism, and the probe also demonstrated reversibility and INHIBIT/IMPLICATION Logic gate behavior with EDTA for the HNTCH-Zn2+ complex.
INORGANICA CHIMICA ACTA
(2021)
Article
Biochemical Research Methods
Puthiyavalappil Rasin, Merlin Mary Mathew, Vipin Manakkadan, Vishnunarayanan Namboothiri Vadakkedathu Palakkeezhillam, Anandaram Sreekanth
Summary: In this work, a highly selective and sensitive fluorescent sensor based on a pyrene derivative was developed for the detection of Fe(III) ions in DMSO/water media. The sensor exhibited fluorescence quenching in the presence of Fe(III) ions, with a low limit of detection. The fluorescence lifetime and quantum yield measurements confirmed the binding of the receptor PEBD to Fe(III) ions. Computational studies were conducted to further investigate the properties of the receptor PEBD.
JOURNAL OF FLUORESCENCE
(2022)
Article
Biochemical Research Methods
Puthiyavalappil Rasin, Moideen Musthafa, Anandaram Sreekanth
Summary: We have introduced a novel selenium-based compound for the optical and fluorimetric detection of Hg in an aqueous medium. The compound showed high selectivity and formed a complex with Hg2+ ions. Spectroscopic techniques and computational simulations were used to study the structure and electronic distribution of the compound.
JOURNAL OF FLUORESCENCE
(2022)
Article
Chemistry, Physical
Sabeel M. Basheer, Puthiyavalappil Rasin, Saravana Loganathan Ashok Kumar, Moorthy Saravana Kumar, Anandaram Sreekanth
Summary: 2-acetylpyrzine N-(4)-cyclohexylthiosemicarbazide (H2L) and its Ni(II) and Fe(III) metal complexes were synthesized and studied for their interactions with Bovine Serum Albumin and CT-DNA. The complexes exhibited high affinity for DNA and showed non-covalent intercalation.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Multidisciplinary
Puthiyavalappil Rasin, Vipin Manakkadan, Vishnunarayanan Namboothiri Vadakkedathu Palakkeezhillam, Jebiti Haribabu, Cesar Echeverria, Anandaram Sreekanth
Summary: A pyrene-based fluorescent chemosensor APSB was designed and synthesized, which selectively binds Fe3+ ions and shows high selectivity and sensitivity. The function of APSB can be explained by the photo-induced electron transfer mechanism and its efficiency for selective detection of Fe3+ in cells was confirmed.
Article
Chemistry, Physical
Vishnunarayanan Namboothiri Vadakkedathu Palakkeezhillam, Jebiti Haribabu, Vipin Manakkadan, Puthiyavalappil Rasin, Roslin Elsa Varughese, Dasararaju Gayathri, Nattamai Bhuvanesh, Cesar Echeverria, Anandaram Sreekanth
Summary: In this study, we synthesized and evaluated the biological activity of new thiosemicarbazones and their cyclized heterocyclic compounds through in silico and in vitro examinations. Two pyrene-based thiosemicarbazone compounds were prepared and two new compounds were obtained through cyclization reactions. The structure of the compounds was characterized using various analytical techniques. Among them, PP2 exhibited strong cytotoxicity and inhibited the growth of HepG-2 and T24 cells.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Multidisciplinary
Merlin Mary Mathew, Puthiya Valappil Rasin, Priyabrata Mandal, Anandaram Sreekanth
Summary: This study develops two chemosensors, 3TCH and BTTCH, using photoluminescence spectroscopy (PL) to detect hazardous metal ions and anions, such as Cu2+, F-, and AcO-, in industrial and domestic water. Spectral variations and color changes indicate their interaction and the detection limits are low. The chemosensor 3TCH + F- shows the highest association constant and affinity. Furthermore, the compatibility of these chemosensors with common household items like mouthwash and vinegar is investigated.
RESULTS IN CHEMISTRY
(2023)
Article
Chemistry, Analytical
Puthiyavalappil Rasin, Praveena Prabhakaran, Sabeel M. Basheer, Vipin Manakkadan, Vishnunarayanan Namboothiri Vadakkedathu Palakkeezhillam, Anandaram Sreekanth
Summary: We described a cheap and effective chemosensor (NHPyTSC) that can differentiate Hg2+ and Zn2+ ions from other metal ions. Spectroscopy techniques revealed noticeable color and absorption changes when mercury and zinc ions were added to the chemosensor. The addition of EDTA in NHPyTSC-Hg2+ and NHPyTSC-Zn2+ solutions allowed for colorimetry readings to be reversed. Additionally, the chemosensor showed potential applications in molecular information processing, molecular keypad lock, molecular logic gates, and latent fingerprint detection.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Physical
Puthiyavalappil Rasin, Jebiti Haribabu, Kailas Mahipal Malappuram, Vipin Manakkadan, Vishnunarayanan Namboothiri Vadakkedathu Palakkeezhillam, Cesar Echeverria, Anandaram Sreekanth
Summary: A pyrene-based fluorescence sensor, PyAP, was developed for the specific detection of Ga3+ ions through a simple Schiff base reaction. It showed good selectivity and sensitivity in the presence of other metal ions. The binding constant between PyAP and Ga3+ was determined to be 7.03 x 104 M-1, with a detection limit of 3.35 nM in a DMSO/H2O (2:8, v/v) solution. The sensor's ability to detect Ga3+ in living cells and its cell permeability were validated through live cell imaging in T24 cells. Furthermore, PyAP was found to have applications in molecular logic gates and keypad locks.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Article
Electrochemistry
Sabeel M. Basheer, S. L. Ashok Kumar, N. Sarathi, Puthiyavalappil Rasin, M. Saravana Kumar, Mathiyan Muralisankar, A. Sreekanth
Summary: A novel corrosion inhibitor DTSc has been developed and characterized using different spectroscopic techniques. Its effectiveness in protecting mild steel from corrosion in HCl has been evaluated using various corrosion monitoring techniques. The adsorption of DTSc on the mild steel surface was found to be chemisorption. The inhibition efficiency of DTSc increased with concentration and immersion time, and the presence of the inhibitor eliminated corrosion-related surface imperfections.
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
(2023)
Article
Chemistry, Applied
Vishnunarayanan Namboothiri Vadakkedathu Palakkeezhillam, Jebiti Haribabu, Vaishnu Suresh Kumar, Vipin Manakkadan, Puthiyavalappil Rasin, Nattamai Bhuvanesh, Cesar Echeverria, Juan F. Santibanez, Anandaram Sreekanth
Summary: A series of thiosemicarbazones were synthesized and evaluated for their anticancer activity. One compound (CFM) showed potent inhibitory effects against breast adenocarcinoma and urinary bladder cancer cells, while exhibiting negligible cytotoxicity against normal cells. Molecular docking studies suggested effective binding of these compounds with cancer proteins and serum proteins. These findings provide insights into the bioactivities of thiosemicarbazones.
APPLIED ORGANOMETALLIC CHEMISTRY
(2023)
Article
Chemistry, Physical
Vipin Manakkadan, Jebiti Haribabu, Vishnunarayanan Namboothiri Vadakkedathu Palakkeezhillam, Puthiyavalappil Rasin, Manas Mandal, Vaishnu Suresh Kumar, Nattamai Bhuvanesh, Rednam Udayabhaskar, Anandaram Sreekanth
Summary: In this study, a series of thiosemicarbazones were synthesized and their structures were confirmed using various spectroscopic techniques. The compounds showed interactions with CT-DNA and BSA, with TL3 exhibiting stronger binding and interaction. Computational evaluations revealed TL2 to have higher structural stability. All compounds showed potential as oral drug candidates. TL3 exhibited good anticancer activity in liver and endothelial carcinoma cells.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Multidisciplinary
Merlin Mary Mathew, A. Sreekanth
Summary: Two novel N4-suberene substituted thiosemicarbazone chemosensors (SATSC 1 and SATSC 2) designed and synthesised for colorimetric and optical response towards anions show good sensing responses towards fluoride, acetate and cyanide ions. SATSC 2 exhibits better binding affinity towards fluoride ions than SATSC 1, and both sensors display fluorescent enhancement after binding with certain anions.
JOURNAL OF CHEMICAL SCIENCES
(2021)
Article
Chemistry, Multidisciplinary
Zihan Ma, Lishuang Wang, Tingting Chen, Guangning Wang
Summary: In this study, two kinds of 3D self-doped (N/O) lilac-based and coriander-based porous carbons with high performance have been prepared.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Qin Wang, Yun-Fan Yan, Jiao-Lin Weng, Ying Huang, Fu Yang, Hao-Hui Xie, Fei Tan, Fa-Kun Zheng, Jian-Gang Xu
Summary: Balancing energy and mechanical sensitivities is a challenging issue in the field of energetic materials. This study constructed a 3D energetic metal-organic framework with nitrogen-rich ligand and NO3- anions. The framework demonstrated high stability, energy density, and excellent mechanical sensitivities, making it a potential insensitive energetic material.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Marrium Saeed, Urooj Kamran, Amina Khan, Md Irfanul Haque Siddiqui, Hasan Jamal, Haq Nawaz Bhatti
Summary: In this study, magnesium-aluminum layered double hydroxides (Mg-Al-LDH) were synthesized using an environmentally friendly hydrothermal technique for adsorbing the dye reactive green 5 (RG5). To improve the adsorption capability, composites were prepared by combining Mg-Al-LDH with low-cost Mangifera indica stone biomass (MISB). The results showed that the composites had high adsorption capacities for RG5 dye and could be regenerated.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Xuanlin Zhan, Xiaojie Li, Yunyan Zeng, Siyan Jiang, Chao Pan, Shiyu Pan, Jiaquan Huang, Heqian Zhang, Zhiwei Qin
Summary: This study reports on the potential prospects of natural products derived from the rhizosphere for the development of antibiotics and herbicides, as well as the advancements in cultivating a mutant strain that produces a substantial quantity of lydicamycins, a potent family for herbicide development.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Jie Zhu, Jiangtao Yu, Linhua Zhu, Xiaoxiao Yu, Jixing Liu, Yanhong Chao, Jingzhou Yin, Peiwen Wu, Jian Liu, Wenshuai Zhu
Summary: This study successfully demonstrates the 3D printing of attapulgite monoliths and investigates the influence of thermal treatment on their properties. The thermal treated monoliths show superior catalytic performance at low temperatures.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yanzhu Ye, Yixiang Ye, Jiannan Cai, Zhongshui Li, Shen Lin
Summary: In this paper, a novel Pt/CoP/C photo-electro synergistic catalyst was successfully synthesized and its performance was investigated. The catalyst exhibited excellent photo-electro catalytic performance, with significantly higher hydrogen production compared to a commercial catalyst. The introduction of cobalt phosphide and the existence of Co3O4 were identified as key factors for enhancing the catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nurul Hidayah Abu Bakar, Wan Norfazilah Wan Ismail, Hartina Mohd Yusop, Noreen Farzuhana Mohd Zulkifli
Summary: Hydrophobic coatings inspired by the lotus effect have gained popularity for their ability to solve various problems. The sol-gel method, utilizing silica, alumina, and titania, is explored as an environmentally friendly approach to produce water-based hydrophobic coatings. This study focuses on producing water-based hydrophobic coatings for cotton and polyester fabrics using a one-step sol-gel method. The coated fabrics exhibited improved hydrophobic properties, altered surface morphologies, and lower air permeability compared to uncoated fabrics. TEOS-PDMS coating provides a promising approach for enhancing the hydrophobic and surface properties of cotton and polyester fabrics.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nikita Belko, Hanna Maltanava, Anatol Lugovski, Polina Shabunya, Sviatlana Fatykhava, Evgeny Bondarenko, Pavel Chulkin, Sergey Poznyak, Michael Samtsov
Summary: This study investigates the difference in electrochemical behavior between rhodamine B hydrazide and rhodamine B acylhydrazone, and finds that rhodamine B acylhydrazone exhibits higher reversibility in electrooxidation. These results can be applied for developing new sensors with desired electrochemical properties.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Showket Ahmad Bhat, Mohd Ikram
Summary: In this study, 0-3 particulate multiferroic composites were synthesized and characterized. The composites exhibited excellent ferroelectric and ferromagnetic properties, as well as high piezoelectric strain and magnetoelectric coupling effects.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Carla Gomes, Mariana Costa, Susana M. M. Lopes, Bernardo Albuquerque Nogueira, Rui Fausto, Jose A. Paixao, Teresa M. V. D. e Melo, Luisa M. D. R. S. Martins, Marta Pineiro
Summary: The development of sustainable processes requires the integration of green chemistry principles. In this study, a solvent-free synthesis method was developed to prepare new copper catalysts, which efficiently catalyze cycloaddition reactions under solvent-free mechanochemical conditions. Through this process, the principles of atom economy, reduction of solvents and auxiliaries, design for energy efficiency, and reduction of derivatives and catalysis are combined.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Zhihua Liu, Jinzhe Li, Jianguo Zhou
Summary: This study demonstrates the enhancement of photoelectrochemical activity of BiFeO3 photoelectrodes through ion modification, which increases visible light absorption and active area, leading to improved PEC water splitting performance.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yisheng Zhang, Wensong Li, Jing Li, Fang Li, Wei Xue, Xinqiang Zhao, Yanji Wang
Summary: Pt/C and SO42-/ZrO2 were used as catalysts for the synthesis of p-aminophenol through the catalytic transfer hydrogenation of nitrobenzene in water with formic acid as the hydrogen source. The optimal Pt loading for PAP selectivity was found to be 1 wt%. The presence of different valence states of Pt affected both the nitrobenzene hydrogenation and formic acid decomposition. Among different solid acid catalysts tested, SO42-/ZrO2 exhibited the highest catalytic activity for p-aminophenol formation. Under the optimized reaction conditions, the conversion of nitrobenzene reached 80.0%, with a selectivity of 47.6% for p-aminophenol.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Pradyota Kumar Behera, Papita Behera, Amlan Swain, Santosh Kumar Sahu, Ajeena Sahoo, Laxmidhar Rout
Summary: We have developed a simple and direct method for the synthesis of diaryl ether using an oxygen bridged bimetallic CuMoO4 nanocatalyst under mild reaction conditions. The catalyst exhibited tolerance towards a wide range of substrates with various functional groups. It is efficient and recyclable. This methodology allows easy access to nitrofen derivatives (herbicides) from unactivated 2,4-dichlorophenol, which are important for agriculture and pharmaceuticals.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yihua Fu, Yan Zhang, Changwei Hu, Zhishan Su
Summary: The mechanism of the reaction between CO2 and styrene oxide for cyclic carbonate was revealed using density functional theory calculations. The noncatalytic reaction occurred via a concerted mechanism, while in the presence of guanidine and tetrabutylammonium iodide (TBAI) co-catalysts, the epoxide ring-opening by nucleophilic attack of an iodide anion was predicted to be the rate-determining step. Guanidine acted as the H-bond donor to activate styrene oxide, facilitating the reaction with a lower activation barrier.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Saikat Khamarui, Sirshendu Ghosh
Summary: Copper nanorods (Cu-NRs) exhibit significant plasmonic behavior and can act as efficient catalysts in redox processes and coupling. A benign decarboxylative approach, utilizing localized surface plasmon resonance (LSPR) assisted catalysis with Cu-NRs, has been developed for the production of alkane analogues from alkyl carboxylic acids under visible light. The catalyst shows a broad substrate scope and high functional group tolerance, without the need for an external oxidant or proton source. A plausible mechanism for this recyclable nano-catalyst has also been proposed based on control experiments.
NEW JOURNAL OF CHEMISTRY
(2024)