期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 357, 期 6, 页码 1181-1186出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400983
关键词
arylboronic acids; cross-coupling; nickel; sulfonyl hydrazides; sulfur; synthetic methods
资金
- Department of Biotechnology, New Delhi [BT/PR13339/BRB/10/750/2009]
A practical nickel-catalysed approach has been developed for the C-S bond formation through the cross-coupling of arylsulfonyl hydrazides and aryl boronic acids. The report employs arylsulfonyl hydrazide as an aryl thiol equivalent and offers a mild and eco-safe synthesis of unsymmetrical thioethers in good to excellent yields in air. The scope and versatility of the method has been successfully demonstrated with 22 examples.
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