The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations

Catalytic aerobic oxidation of renewable furfural to maleic anhydride and furanone derivatives with their mechanistic studies

(2014) Jihong Lan et al.   GREEN CHEMISTRY

Redox Inactive Metal Ion Promoted CH Activation of Benzene to Phenol with PdII(bpym): Demonstrating New Strategies in Catalyst Designs

(2013) Huajun Guo et al.   Chemistry-An Asian Journal

Lewis-Acid-Promoted Stoichiometric and Catalytic Oxidations by Manganese Complexes Having Cross-Bridged Cyclam Ligand: A Comprehensive Study

(2013) Lei Dong et al.   INORGANIC CHEMISTRY

Synthesis and Structural Characterization of a Series of MnIIIOR Complexes, Including a Water-Soluble MnIIIOH That Promotes Aerobic Hydrogen-Atom Transfer

(2013) Michael K. Coggins et al.   INORGANIC CHEMISTRY

Origin of the high activity of Au/FeOx for low-temperature CO oxidation: Direct evidence for a redox mechanism

(2013) Lin Li et al.   JOURNAL OF CATALYSIS

Kinetics of hydrogen abstraction by active metal hydroxo and oxo intermediates: revealing their unexpected similarities in the transition state

(2012) Yujuan Wang et al.   CHEMICAL COMMUNICATIONS

Electron-transfer properties of a nonheme manganese(iv)–oxo complex acting as a stronger one-electron oxidant than the iron(iv)–oxo analogue

(2012) Heejung Yoon et al.   CHEMICAL COMMUNICATIONS

Electron-transfer properties of high-valent metal-oxo complexes

(2012) Shunichi Fukuzumi   COORDINATION CHEMISTRY REVIEWS

Influence of the Net Charge on the Reactivity of a Manganese(IV) Species: Leading to the Correlation of Its Physicochemical Properties with Reactivity

(2012) Yujuan Wang et al.   Journal of Physical Chemistry C

Proton-Promoted Oxygen Atom Transfer vs Proton-Coupled Electron Transfer of a Non-Heme Iron(IV)-Oxo Complex

(2012) Jiyun Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

(2012) W. Liu et al.   SCIENCE

Evidence for a Precursor Complex in CH Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex

(2011) Isaac Garcia-Bosch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Distinct Reactivity Differences of Metal Oxo and Its Corresponding Hydroxo Moieties in Oxidations: Implications from a Manganese(IV) Complex Having Dihydroxide Ligand

(2011) Song Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic oxidation of hydrocarbons with hydrogen peroxide by vanadium-based polyoxometalates

(2011) Noritaka Mizuno et al.   COORDINATION CHEMISTRY REVIEWS

On the Reactivity of Mononuclear Iron(V)oxo Complexes

(2011) Soumen Kundu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid C–H Bond Activation by a Monocopper(III)–Hydroxide Complex

(2011) Patrick J. Donoghue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal Ion Effect on the Switch of Mechanism from Direct Oxygen Transfer to Metal Ion-Coupled Electron Transfer in the Sulfoxidation of Thioanisoles by a Non-Heme Iron(IV)−Oxo Complex

(2011) Jiyun Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Manganese Catalysts for C−H Activation: An Experimental/Theoretical Study Identifies the Stereoelectronic Factor That Controls the Switch between Hydroxylation and Desaturation Pathways

(2010) Jonathan F. Hull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron Transfer−Oxygen Transfer Oxygenation of Sulfides Catalyzed by the H5PV2Mo10O40Polyoxometalate

(2010) Alexander M. Khenkin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal Ion-Coupled Electron Transfer of a Nonheme Oxoiron(IV) Complex: Remarkable Enhancement of Electron-Transfer Rates by Sc3+

(2010) Yuma Morimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Distinct Oxygenation Difference between Manganese(IV) Hydroxo and Oxo Moieties: Electron Transfer versus Concerted Oxygen Transfer

(2009) Aihua Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivities of Fe(IV) Complexes with Oxo, Hydroxo, and Alkylperoxo Ligands: An Experimental and Computational Study

(2009) Adam T. Fiedler et al.   INORGANIC CHEMISTRY

Mechanistic Investigations of the Reaction of an Iron(III) Octa-Anionic Porphyrin Complex with Hydrogen Peroxide and the Catalyzed Oxidation of Diammonium-2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonate)

(2009) Ariane Brausam et al.   INORGANIC CHEMISTRY

Enantioselective epoxidation of olefins with molecular oxygen catalyzed by gold(III): A dual pathway for oxygen transfer

(2009) Avelino Corma et al.   JOURNAL OF CATALYSIS

Mechanistic Insights into Hydride-Transfer and Electron-Transfer Reactions by a Manganese(IV)−Oxo Porphyrin Complex

(2009) Shunichi Fukuzumi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Cleavage with Reductants: Re-Investigating the Reactivity of Monomeric MnIII/IV−Oxo Complexes and the Role of Oxo Ligand Basicity

(2009) Trenton H. Parsell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium Porphyrin-Catalyzed Aerobic Oxidation of Terminal Aryl Alkenes to Aldehydes by a Tandem Epoxidation-Isomerization Pathway

(2008) Gaoxi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transient Intermediates from Mn(salen) with Sterically Hindered Mesityl Groups: Interconversion between MnIV-Phenolate and MnIII-Phenoxyl Radicals as an Origin for Unique Reactivity

(2008) Takuya Kurahashi et al.   INORGANIC CHEMISTRY

Oxidative Reactivity Difference among the Metal Oxo and Metal Hydroxo Moieties: pH Dependent Hydrogen Abstraction by a Manganese(IV) Complex Having Two Hydroxide Ligands

(2008) Guochuan Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing the Compound I-like Reactivity of a Bare High-Valent Oxo Iron Porphyrin Complex:  The Oxidation of Tertiary Amines

(2008) Barbara Chiavarino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY