期刊
CHEMICAL RECORD
卷 16, 期 1, 页码 84-97出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201500218
关键词
biaryls; cross-coupling; homogeneous catalysis; palladium; Suzuki-Miyaura reaction
资金
- National Natural Science Foundation of China [21276043, 21076034, 21421005]
- Ministry of Education (Program for New Century Excellent Talents in University) [NCET-10-0283]
As one of the most powerful and versatile methods for the construction of carbon-carbon bonds, the Suzuki-Miyaura cross-coupling reaction has attracted great attention over the past three decades. In recent years, a huge amount of interest has been focused on the development of ligand-free Suzuki-Miyaura reaction systems, which have the advantages of low cost, mild reaction conditions, and easy operation. So far, a number of ligand-free Suzuki-Miyaura reaction systems have been developed by using simple palladium salts, nanopalladium, or supported palladium catalysts. In this account, we will review our recent research on the oxygen-promoted ligand-free Suzuki-Miyaura reaction. Interestingly, the oxygen-promoting effect has been observed in different reaction media, including polyethylene glycol, organic/water mixed solvents and pure water. The oxygen-promoted reaction systems demonstrate high efficiency for the construction of biaryls.
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