4.8 Article

Defect segregation and optical emission in ZnO nano- and microwires

期刊

NANOSCALE
卷 8, 期 14, 页码 7631-7637

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nr08248j

关键词

-

资金

  1. National Science Foundation [DMR-1305193]
  2. Deutsche Forschungsgemeinschaft [Gr 1011/26-1]
  3. Norwegian Research council [221992]
  4. Direct For Mathematical & Physical Scien [1305193] Funding Source: National Science Foundation

向作者/读者索取更多资源

The spatial distribution of defect related deep band emission has been studied in zinc oxide (ZnO) nano- and microwires using depth resolved cathodoluminescence spectroscopy (DRCLS) in a hyperspectral imaging (HSI) mode within a UHV scanning electron microscope (SEM). Three sets of wires were examined that had been grown by pulsed laser deposition or vapor transport methods and ranged in diameter from 200 nm-2.7 mu m. This data was analyzed by developing a 3D DRCLS simulation and using it to estimate the segregation depth and decay profile of the near surface defects. We observed different dominant defects from each growth process as well as diameter-dependent defect segregation behavior.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

Mid- and far-infrared localized surface plasmon resonances in chalcogen-hyperdoped silicon

Mao Wang, Ye Yu, Slawomir Prucnal, Yonder Berencen, Mohd Saif Shaikh, Lars Rebohle, Muhammad Bilal Khan, Vitaly Zviagin, Rene Hubner, Alexej Pashkin, Artur Erbe, Yordan M. Georgiev, Marius Grundmann, Manfred Helm, Robert Kirchner, Shengqiang Zhou

Summary: The occurrence of mid-infrared localized surface plasmon resonances (LSPR) in thin Si films hyperdoped with tellurium (Te) is demonstrated in this study. By fabricating two-dimensional arrays of micrometer-sized antennas in a Te-hyperdoped Si chip, the mid-infrared LSPR can be further enhanced and extended to the far-infrared range. This finding opens up the possibility of integrating plasmonic sensors with the on-chip CMOS platform, greatly advancing the mass manufacturing potential of high-performance plasmonic sensing systems.

NANOSCALE (2022)

Article Materials Science, Multidisciplinary

Band Alignment of Al2O3 on α-(AlxGa1-x)2O3

Xinyi Xia, Nahid Sultan Al-Mamun, Chaker Fares, Aman Haque, Fan Ren, Anna Hassa, Holger von Wenckstern, Marius Grundmann, S. J. Pearton

Summary: This study used X-ray photoelectron spectroscopy to measure the valence band offsets of Al2O3 deposited on α-(AlxGa1-x)(2)O-3 alloys. The results showed that the band alignment was type I at lower Al contents and staggered at higher Al contents.

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY (2022)

Article Materials Science, Multidisciplinary

Epitaxial lift-off of single crystalline CuI thin films

Philipp Storm, Susanne Selle, Holger von Wenckstern, Marius Grundmann, Michael Lorenz

Summary: Transparent, p-type semiconductor copper iodide (CuI) thin films were grown via pulsed laser deposition on SrF2(111) using water soluble sacrificial layers of sodium bromide (NaBr). The resulting CuI thin films are single crystalline with reduced surface roughness compared to epitaxial CuI grown with rotational domains on other templates. The CuI thin films were subsequently transferred onto glass using epoxy/glue and dissolution of NaBr in a water-vapor atmosphere.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Optics

Combination of a global-search method with model selection criteria for the ellipsometric data evaluation of DLC coatings

K. Dorywalski, O. Lupicka, M. Grundmann, C. Sturm

Summary: A new method for evaluating experimental data from spectroscopic ellipsometry is proposed, which combines the global-search optimization algorithm with statistical model selection criteria. This method is able to find the optical model parameters and select the optimal dielectric function model for describing the optical properties of materials even with limited initial knowledge.

ADVANCED OPTICAL TECHNOLOGIES (2022)

Article Physics, Condensed Matter

Epitaxial Growth of AgxCu1-xI on Al2O3(0001)

Evgeny Krueger, Volker Gottschalch, Gabriele Benndorf, Ron Hildebrandt, Ana Lucia Pereira, Michael S. Bar, Steffen Blaurock, Stefan Merker, Chris Sturm, Marius Grundmann, Harald Krautscheid

Summary: This study presents the epitaxial growth of AgxCu1-xI alloy layers and isolated small crystals on Al2O3 (0001) using the close distance sublimation (CDS) technique. Single-phase gamma-AgxCu1-xI thin films are obtained up to an Ag content of approximately 0.5, with the beta-phase also observed at higher Ag contents. The epitaxial relationships between the deposited AgxCu1-xI layers and the Al2O3 substrate, as well as the structure type, are discussed for different alloy compositions. Additionally, a method for depositing polycrystalline single-phase gamma-AgxCu1-xI thin films for Ag contents up to approximately 0.7 is presented based on the solid-state reaction of AgI layers on Al2O3 (0001) substrate with CuI. Furthermore, it is shown that the near-band-edge emission at 2 K is dominated by excitonic recombination, and the spectral position of the emission profile can be tuned by the alloy composition.

PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS (2023)

Article Nanoscience & Nanotechnology

Origin of enhanced conductivity in low dose ion irradiated oxides

Jon Borgersen, Robert Karsthof, Vegard Ronning, Lasse Vines, Holger von Wenckstern, Marius Grundmann, Andrej Yu Kuznetsov, Klaus Magnus Johansen

Summary: Significant resistivity variations have been observed in oxides subjected to low ion doses, which cannot be explained by bulk defects. A comparative study of In2O3-based oxides revealed correlations between resistivity evolution, low ion doses, and UV illumination. The resistivity drops were attributed to oxygen desorption facilitated by irradiation/illumination, as confirmed by post-irradiation exposure to oxygen atmosphere.

AIP ADVANCES (2023)

Article Nanoscience & Nanotechnology

Highly crystalline In2S3 thin films epitaxially grown on sapphire substrates

Tanja Jawinski, Chris Sturm, Roland Clausing, Heiko Kempa, Marius Grundmann, Roland Scheer, Holger von Wenckstern

Summary: In this study, indium sulfide (In2S3) thin films were deposited on glass and sapphire substrates by physical co-evaporation. The structural properties of the films were optimized by varying the deposition parameters. The sample grown epitaxially on an α-sapphire substrate exhibited the smoothest surface and highest crystallinity. The optical absorption properties were found to be independent of the deposition parameters and substrate material. Weak and strong absorption onsets were observed at 1.7 eV and 2.5 eV, respectively, which were attributed to direct band-band transitions at 2.1 eV and 2.7 eV. The electrical characterization revealed photovoltaic activity but low performance due to non-ideal heterojunction properties. A strong and persistent photoconductivity was also observed, resulting in a time-dependent dark resistivity after light exposure.

AIP ADVANCES (2022)

Article Materials Science, Multidisciplinary

Dielectric function of CuBrxI1-x alloy thin films

Michael Seifert, Evgeny Krueger, Michael S. Bar, Stefan Merker, Holger von Wenckstern, Harald Krautscheid, Marius Grundmann, Chris Sturm, Silvana Botti

Summary: We studied the dielectric function of CuBrxI1-x thin film alloys using spectroscopic ellipsometry and density functional theory calculations. The features in the dielectric function were attributed to electronic transitions at specific k-points in the Brillouin zone, and the band gap bowing was discussed in terms of physical and chemical contributions. The band splitting at the top of the valence band decreased with increasing Br-concentration, which can be understood by considering the contribution of copper d orbitals to the valence band maximum.

PHYSICAL REVIEW MATERIALS (2022)

Review Materials Science, Coatings & Films

Masked-assisted radial-segmented target pulsed-laser deposition: A novel method for area-selective deposition using pulsed-laser deposition

Laurenz Thyen, Daniel Splith, Max Kneiss, Marius Grundmann, Holger von Wenckstern

Summary: We introduce a new technique, MARS-PLD, for area-selective physical vapor deposition. By using a movable mask, we can selectively mask any desired area on a substrate to create multinary material composition gradients. We demonstrated the capabilities of this method by fabricating material gradients in (Mg,Zn)O thin films and on predefined two-dimensional patterns.

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A (2023)

Article Nanoscience & Nanotechnology

Optical properties of AgxCu1-xI alloy thin films

Evgeny Krueger, Michael Seifert, Volker Gottschalch, Harald Krautscheid, Claudia S. Schnohr, Silvana Botti, Marius Grundmann, Chris Sturm

Summary: We studied the excitonic transition energy E-0 and spin-orbit split-off energy Delta(0) of gamma-AgxCu1-xI alloy thin films using reflectivity measurements at temperatures between 20 K and 290 K. The observed bowing behavior of the E-0 transition as a function of alloy composition is explained based on first-principles band structure calculations. The spin-orbit coupling increases with increasing Ag-content, and the temperature-dependent bandgap shift decreases with increasing Ag-content.

AIP ADVANCES (2023)

Article Physics, Applied

Two- and three-photon absorption in bulk CuI

Andreas Mueller, Sebastian Henn, Evgeny Krueger, Steffen Blaurock, Harald Krautscheid, Marius Grundmann, Chris Sturm

Summary: We report on the photoluminescence emission in copper iodide bulk single crystals induced by two- and three-photon absorption around 1.525eV. The non-linear optical processes were investigated through density-dependent, steady-state, and time-resolved photoluminescence spectroscopy. We observed that the photoluminescence intensity showed an almost parabolic behavior with the excitation power when the excitation energy corresponded to half of the bandgap energy. We also found a cubic contribution that increased with decreasing excitation energy. The ratio between the two- and three-photon absorption cross sections was determined to be approximately 10(-28) cm(2)s.

APPLIED PHYSICS LETTERS (2023)

Article Physics, Condensed Matter

Space Charge Region beyond the Abrupt Approximation

Marius Grundmann

Summary: This study revisits the problem of potential, electrical field, and charge density in a space charge region. Using the Boltzmann approximation, an analytical asymptotic solution is obtained. The exact solution can be found by numerically integrating an analytical function. A comparison is made with the popular abrupt (or depletion) approximation, and an analytical approximation is provided. The analytical approximation for potential, electrical field, and charge density in a space charge (depletion) region shows good agreement with the (numerically) exact solution.

PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS (2023)

Article Instruments & Instrumentation

Flexible hardware concept of pulsed laser deposition for large areas and combinatorial composition spreads

Michael Lorenz, Holger Hochmuth, Holger von Wenckstern, Marius Grundmann

Summary: Pulsed laser deposition (PLD) is a highly flexible physical growth technique for thin films of functional materials. This article describes a relatively simple and reliable concept of PLD hardware that enables deposition on large areas (up to 4 inches in diameter) and tailored lateral and vertical composition spreads without the need for time-consuming hardware changes. Different PLD approaches have been implemented in various chambers by using specific and correlated computer-controlled movements of the target, substrate, and masks, along with an appropriate target phase composition.

REVIEW OF SCIENTIFIC INSTRUMENTS (2023)

Article Nanoscience & Nanotechnology

Oxygen Plasma Treatment to Enable Indium Oxide MESFET Devices

Fabian Schoeppach, Daniel Splith, Holger von Wenckstern, Marius Grundmann

Summary: In this study, metal-semiconductor field-effect transistor (MESFET) devices based on pulsed laser deposition (PLD) grown In2O3 thin films are reported. These devices exhibit on-off ratios exceeding 6 orders of magnitude and low sub-threshold swing values close to the thermodynamic limit. Oxygen plasma treatment and compensation doping with Mg are used to suppress the accumulation of electrons at the surface of In2O3, which is a major obstacle for its use as an active material in electronic devices.

ADVANCED ELECTRONIC MATERIALS (2023)

Article Materials Science, Multidisciplinary

Preferential growth of perovskite BaTiO3 thin films on Gd3Ga5O12(100) and Y3Fe5O12(100) oriented substrates by pulsed laser deposition

Thomas Ruf, Stefan Merker, Frank Syrowatka, Philip Trempler, Georg Schmidt, Michael Lorenz, Marius Grundmann, Reinhard Denecke

Summary: This study focuses on the structural compatibility of perovskite BaTiO3 on garnet substrates Gd3Ga5O12 and Y3Fe5O12, with a particular emphasis on the growth behavior on different garnet orientations. It was found that BaTiO3 growth on the garnet (100) orientation showed good crystallinity, while growth on other orientations resulted in polycrystalline films.

MATERIALS ADVANCES (2022)

Article Chemistry, Multidisciplinary

Exploring the degradation of silver nanowire networks under thermal stress by coupling in situ X-ray diffraction and electrical resistance measurements

Laetitia Bardet, Herve Roussel, Stefano Saroglia, Masoud Akbari, David Munoz-Rojas, Carmen Jimenez, Aurore Denneulin, Daniel Bellet

Summary: The thermal instability of silver nanowires leads to increased electrical resistance in AgNW networks. Understanding the relationship between structural and electrical properties of AgNW networks is crucial for their integration as transparent electrodes in flexible optoelectronics. In situ X-ray diffraction measurements were used to study the crystallographic evolution of Ag-specific Bragg peaks during thermal ramping, revealing differences in thermal and structural transitions between bare and SnO2-coated AgNW networks.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Recording physiological and pathological cortical activity and exogenous electric fields using graphene microtransistor arrays in vitro

Nathalia Cancino-Fuentes, Arnau Manasanch, Joana Covelo, Alex Suarez-Perez, Enrique Fernandez, Stratis Matsoukis, Christoph Guger, Xavi Illa, Anton Guimera-Brunet, Maria V. Sanchez-Vives

Summary: This study provides a comprehensive characterization of graphene-based solution-gated field-effect transistors (gSGFETs) for brain recordings, highlighting their potential clinical applications.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Metal oxide-embedded carbon-based materials for polymer solar cells and X-ray detectors

Sikandar Aftab, Hailiang Liu, Dhanasekaran Vikraman, Sajjad Hussain, Jungwon Kang, Abdullah A. Al-Kahtani

Summary: This study examines the effects of hybrid nanoparticles made of NiO@rGO and NiO@CNT on the active layers of polymer solar cells and X-ray photodetectors. The findings show that these hybrid nanoparticles can enhance the charge carrier capacities and exciton dissociation properties of the active layers. Among the tested configurations, the NiO@CNT device demonstrates superior performance in converting sunlight into electricity, and achieves the best sensitivity for X-ray detection.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Peptide-mediated targeted delivery of SOX9 nanoparticles into astrocytes ameliorates ischemic brain injury

Hyo Jung Shin, Seung Gyu Choi, Fengrui Qu, Min-Hee Yi, Choong-Hyun Lee, Sang Ryong Kim, Hyeong-Geug Kim, Jaewon Beom, Yoonyoung Yi, Do Kyung Kim, Eun-Hye Joe, Hee-Jung Song, Yonghyun Kim, Dong Woon Kim

Summary: This study investigates the role of SOX9 in reactive astrocytes following ischemic brain damage using a PLGA nanoparticle plasmid delivery system. The results demonstrate that PLGA nanoparticles can reduce ischemia-induced neurological deficits and infarct volume, providing a potential opportunity for stroke treatment.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Spontaneous unbinding transition of nanoparticles adsorbing onto biomembranes: interplay of electrostatics and crowding

Anurag Chaudhury, Koushik Debnath, Nikhil R. Jana, Jaydeep K. Basu

Summary: The study investigates the interaction between nanoparticles and cell membranes, and identifies key parameters, including charge, crowding, and membrane fluidity, that determine the adsorbed concentration and unbinding transition of nanoparticles.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Autonomous nanomanufacturing of lead-free metal halide perovskite nanocrystals using a self-driving fluidic lab

Sina Sadeghi, Fazel Bateni, Taekhoon Kim, Dae Yong Son, Jeffrey A. Bennett, Negin Orouji, Venkat S. Punati, Christine Stark, Teagan D. Cerra, Rami Awad, Fernando Delgado-Licona, Jinge Xu, Nikolai Mukhin, Hannah Dickerson, Kristofer G. Reyes, Milad Abolhasani

Summary: In this study, an autonomous approach for the development of lead-free metal halide perovskite nanocrystals is presented, which integrates a modular microfluidic platform with machine learning-assisted synthesis modeling. This approach enables rapid and optimized synthesis of copper-based lead-free nanocrystals.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

In situ growth of a redox-active metal-organic framework on electrospun carbon nanofibers as a free-standing electrode for flexible energy storage devices

Zahir Abbas, Nissar Hussain, Surender Kumar, Shaikh M. Mobin

Summary: The rational construction of free-standing and flexible electrodes for electrochemical energy storage devices is an emerging research focus. In this study, a redox-active metal-organic framework (MOF) was prepared on carbon nanofibers using an in situ approach, resulting in a flexible electrode with high redox-active behavior and unique properties such as high flexibility and lightweight. The prepared electrode showed excellent cyclic retention and rate capability in supercapacitor applications. Additionally, it could be used as a freestanding electrode in flexible devices at different bending angles.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

A NIR-driven green affording-oxygen microrobot for targeted photodynamic therapy of tumors

Lishan Zhang, Xiaoting Zhang, Hui Ran, Ze Chen, Yicheng Ye, Jiamiao Jiang, Ziwei Hu, Miral Azechi, Fei Peng, Hao Tian, Zhili Xu, Yingfeng Tu

Summary: Photodynamic therapy (PDT) is a promising local treatment modality in cancer therapy, but its therapeutic efficacy is restricted by ineffective delivery of photosensitizers and tumor hypoxia. In this study, a phototactic Chlorella-based near-infrared (NIR) driven green affording-oxygen microrobot system was developed for enhanced PDT. The system exhibited desirable phototaxis and continuous oxygen generation, leading to the inhibition of tumor growth in mice. This study demonstrates the potential of using a light-driven green affording-oxygen microrobot to enhance photodynamic therapy.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Novel hollow MoS2@C@Cu2S heterostructures for high zinc storage performance

Yujin Li, Jing Xu, Xinqi Luo, Futing Wang, Zhong Dong, Ke-Jing Huang, Chengjie Hu, Mengyi Hou, Ren Cai

Summary: In this study, hollow heterostructured materials were constructed using an innovative template-engaged method as cathodes for zinc-ion batteries. The materials exhibited fast Zn2+ transport channels, improved electrical conductivity, and controlled volume expansion during cycling. The designed structure allowed for an admirable reversible capacity and high coulombic efficiency.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Mechanistic elucidation of the catalytic activity of silver nanoclusters: exploring the predominant role of electrostatic surface

Paritosh Mahato, Shashi Shekhar, Rahul Yadav, Saptarshi Mukherjee

Summary: This study comprehensively elucidates the role of the core and electrostatic surface of metal nanoclusters in catalytic reduction reactions. The electrostatic surface dramatically modulates the reactivity of metal nanoclusters.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Facile green synthesis of wasted hop-based zinc oxide nanozymes as peroxidase-like catalysts for colorimetric analysis

Pei Liu, Mengdi Liang, Zhengwei Liu, Haiyu Long, Han Cheng, Jiahe Su, Zhongbiao Tan, Xuewen He, Min Sun, Xiangqian Li, Shuai He

Summary: This study demonstrates a simple and environmentally-friendly method for the synthesis of zinc oxide nanozymes (ZnO NZs) using wasted hop extract (WHE). The WHE-ZnO NZs exhibit exceptional peroxidase-like activity and serve as effective catalysts for the oxidation of 3,3,5,5-tetramethylbenzidine (TMB) in the presence of hydrogen peroxide (H2O2). In addition, a straightforward colorimetric technique for detecting both H2O2 and glucose was developed using the WHE-ZnO NZs as peroxidase-like catalysts.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Impact of channel nanostructures of porous carbon particles on their catalytic performance

Hyunkyu Oh, Young Jun Lee, Eun Ji Kim, Jinseok Park, Hee-Eun Kim, Hyunsoo Lee, Hyunjoo Lee, Bumjoon J. Kim

Summary: Mesoporous carbon particles have unique structural properties that make them suitable as support materials for catalytic applications. This study investigates the impact of channel nanostructures on the catalytic activity of porous carbon particles (PCPs) by fabricating PCPs with controlled channel exposure on the carbon surface. The results show that PCPs with highly open channel nanostructures exhibit significantly higher catalytic activity compared to those with closed channel nanostructures.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Fabrication of a tough, long-lasting adhesive hydrogel patch via the synergy of interfacial entanglement and adhesion group densification

Yunjie Lu, Zhaohui Li, Zewei Li, Shihao Zhou, Ning Zhang, Jianming Zhang, Lu Zong

Summary: A tough, long-lasting adhesive and highly conductive nanocomposite hydrogel (PACPH) was fabricated via the synergy of interfacial entanglement and adhesion group densification. PACPH possesses excellent mechanical properties, interfacial adhesion strength, and conductivity, making it a promising material for long-term monitoring of human activities and electrocardiogram signals.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Strongly coupled plasmonic metal nanoparticles with reversible pH-responsiveness and highly reproducible SERS in solution

Zichao Wei, Audrey Vandergriff, Chung-Hao Liu, Maham Liaqat, Mu-Ping Nieh, Yu Lei, Jie He

Summary: We have developed a simple method to prepare polymer-grafted plasmonic metal nanoparticles with pH-responsive surface-enhanced Raman scattering. By using pH-responsive polymers as ligands, the aggregation of nanoparticles can be controlled, leading to enhanced SERS. The pH-responsive polymer-grafted nanoparticles show high reproducibility and sensitivity in solution, providing a novel approach for SERS without the need for sample pre-concentration.

NANOSCALE (2024)

Article Chemistry, Multidisciplinary

Unlocking the full potential of citric acid-synthesized carbon dots as a supercapacitor electrode material via surface functionalization

Melis Ozge Alas Colak, Ahmet Gungor, Merve Buldu Akturk, Emre Erdem, Rukan Genc

Summary: This research investigates the effect of functionalizing carbon dots with hydroxyl polymers on their performance as electrode materials in a supercapacitor. The results show that the functionalized carbon dots exhibit excellent electrochemical performance and improved stability.

NANOSCALE (2024)