期刊
NANO RESEARCH
卷 10, 期 4, 页码 1249-1257出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-016-1351-z
关键词
nanocrystals; necking percolative superlattices; ligand; mobility; trap states
类别
资金
- Chinese ministry of science and technology [2016YFA0200700]
- National Basic Research Program of China [2014CB931801]
- National Natural Science Foundation of China [21473044, 21475029, 91427302]
- Instrument Developing Project of the Chinese Academy of Sciences [YZ201311]
- CAS-CSIRO Cooperative Research Program [GJHZ1503]
- Strategic Priority Research Program of Chinese Academy of Sciences [XDA09040100]
The inter-nanocrystal (NC) distance, necking degree, ordering level, and NC surface ligands all affect the electronic and optoelectronic properties of NC solids. Herein, we introduce a unique PbS structure of necking percolative superlattices to exclude the morphological factors and study the effect of ligands on the NC properties. X-ray photoelectron spectroscopy data indicate that 1,2-ethanedithiol (EDT), oxalic acid, mercaptopropionic acid, and NH4SCN (SCN) ligands were attached to the surface of NCs by substrate-supported ligand exchange. Field-effect transistors were tested and photodetector measurements were performed to compare these NC solids. An SCN-treated film had the highest mobility and responsivity under high-power intensity irradiation owing to its high carrier density, whereas an EDT-treated film had the lowest mobility, photocurrent, and dark current. These findings introduce new avenues for choosing suitable ligands for NC applications.
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