期刊
出版社
WALTER DE GRUYTER GMBH
DOI: 10.1515/znb-2023-0084
关键词
hexafluorophosphates; heat capacity; DSC; Neumann Kopp rule; thermodynamics
The heat capacities of NaPF6 and KPF6 were measured and the suitability of applying a modified Neumann Kopp rule to calculate the heat capacity of PF6 was evaluated to obtain a general method for predicting the heat capacities of other hexafluorophosphates.
The heat capacities of NaPF6 and KPF6 were measured in a broad temperature range using differential scanning calorimetry. The suitability of applying a modified Neumann Kopp rule to calculate the heat capacity of PF6 was evaluated in order to obtain a general method to predict the heat capacities of other hexafluorophosphates.
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