期刊
SOFT MATERIALS
卷 -, 期 -, 页码 -出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/1539445X.2023.2261430
关键词
Hexacatenar; liquid crystal; organogel; phenolphthalein
Different building blocks in organic molecules can form different supramolecular micro/nanostructures through intermolecular interactions. In this study, a new phenolphthalein-based hexacatenar was synthesized by click reaction, which could self-assemble into hexagonal columnar mesophase and form organogel with distinct morphologies in solution. Density functional theory calculations showed that the molecular conformation, charge distribution, and electronic property were important for the stabilization of columnar mesophase and organogel.
Different building blocks in organic molecules could induce complex intermolecular interactions to lead to different supramolecular micro/nanostructures in bulk and solution states. Herein, the first new phenolphthalein-based hexacatenar containing a central phenolphthalein fluorochrome functionalized with two dendritic wings is synthesized by click reaction. The polarized optical microscopy, differential scanning calorimetry, and small-angle X-ray diffraction data demonstrated that the reported phenolphthalein-based hexacatenar could self-assemble into hexagonal columnar mesophase in the bulk state and could form organogel with distinct morphologies in some common organic solvents due to intermolecular interactions. Density functional theory calculation results showed highly twisted molecular conformation, distinct charge distribution, and asymmetrical electronic property, which might be essential for the stabilization of columnar mesophase and organogel. Therefore, this work provides a method to develop soft materials containing different functional building blocks with complex self-assemblies.
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