期刊
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 -, 页码 -出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023623601885
关键词
closo-decaborate anion; amidines; polyfunctional nucleophiles
The reaction between several nitrilium derivatives and hexamethylene- and nonamethylenediamine of the closo-decaborate anion has been investigated. The process involves the functionalization of the amino groups in the nucleophile, resulting in amidines formation.
The reaction of a number of nitrilium derivatives of the closo-decaborate anion with hexamethylene- and nonamethylenediamine has been studied. It has been shown that the process proceeds with the functionalization of both amino groups of the nucleophile to form amidines of the type (Bu4N)(2)[B10H9NH=C(R)NH (CH2)(n)NH(R)C=NHB10H9] (R = CH3, C2H5, (C3H7)-C-n; n = 6, 9). Target compounds have been characterized by high resolution multinuclear NMR and ESI mass spectrometry.
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