Mesoporous TiO2 nanocrystals as efficient photocatalysts: Impact of calcination temperature and phase transformation on photocatalytic performance

Mesoporous TiO2 nanocrystals have been synthesized through sol gel method in presence of triblock copolymer as the structure directing agent. The as-prepared TiO2 nanocrystals have been calcined at different temperatures, i.e., at 400 degrees C, 500 degrees C, 600 degrees C, 700 degrees C, and 800 degrees C to demonstrate how their structural properties (morphology, mesoporosity, crystallite phases and sizes) affect the photocatalytic performance. The TEM images indicate that TiO2 nanocrystals calcined at 500 degrees C have a mesoporous structure with particle sizes of approximately 10-15 nm. However, the TiO2 calcined at 800 degrees C shows a lower mesoporosity and particle sizes of similar to 75 nm. The photocatalytic performance of the newly synthesized photocatalysts has been evaluated through the photodegradation of two different pollutants, i.e., the herbicide imazapyr and phenol, and has been compared to that of the commercially available nonporous AeroxideTiO(2) P-25. For the imazapyr photodegradation, the newly synthesized mesoporous TiO2 nanocrystals show an initial degradation rate around 2 times higher than the rate observed with the non-porous Aeroxide TiO2 P25. The highest photocatalytic activity is observed for the samples calcined at 500 degrees C followed by those calcined at 800 degrees C. In contrast to that, a different behavior is found for the photodegradation of phenol. The results indicate that the TiO2 samples calcined at 500 degrees C show the highest photocatalytic activity for phenol photodegradation. It is proposed that the behavior of the photocatalysts in term of their photocatalytic efficiency and rate constants varies based on the pollutant type. TiO2 calcined at 500 degrees C can be considered as economically more efficient by saving energy through the lower temperature required in the calcination process. (C) 2014 Elsevier B.V. All rights reserved.