Article
Chemistry, Physical
Yue Liu, Jing-zhi Tian, Yong-jie Zheng, He-shan Zheng, Shuo Li, Tao Jing, Hong-rui Zhang, Jing-ying Shao
Summary: A core-shell porous catalyst coated with TiO2-fibrous silica (KCC-1) was prepared and showed excellent catalytic desulfurization performance. The unit desulfurization rate was significantly improved without additional oxidants. The adsorption-catalysis-resorption desulfurization system was effective, enhancing the reaction rate and achieving selective adsorption and coupling desulfurization. Furthermore, the spent catalyst could be regenerated without a decrease in desulfurization rate.
SURFACES AND INTERFACES
(2022)
Article
Engineering, Chemical
Yun Qu, Lei Qin, Yongzhen Yang, Xuguang Liu
Summary: Despite extensive efforts in selective separation membranes, preparing molecularly imprinted membranes with enhanced adsorption capacities and high selectivity remains a strong challenge. In this study, a stepwise imprinting strategy was used to create a composite membrane with functionally modified ordered mesoporous carbon nanospheres for specific and non-destructive extraction of dibenzothiophene. The composite membrane showed outstanding adsorption capacity and excellent relative selectivity factor, mainly due to the interaction between the target molecule and functional groups in the composite structure.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Chemical
Ge Zhang, Fan Yang, Xiaodong Liu, Haiyong Zhao, Sai Che, Jianzhong Li, Xingru Yan, Siyuan Sun, Fengjiang Chen, Chong Xu, Hongchen Liu, Qiang Wei, Yongfeng Li
Summary: This study synthesized N, P co-doped porous carbon network as an efficient absorbent for dibenzothiophene (DBT) removal from oil. The unique micro-mesoporous structure ensured shape-selective adsorption and enhanced DBT adsorption strength. The synergistic effect of N, P co-doping greatly reduced the adsorption energy for DBT, showing significant affinity to DBT.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Energy & Fuels
Xiaoyu Zhou, Hang Liu, Sixiao Liu, Lei Zhang, Tianyi Wang, Chengyin Wang, Dawei Su
Summary: By using the α-Fe2O3/g-C3N4/HNTs composite material, efficient photocatalytic desulfurization of dibenzothiophene in model oil under visible light can be achieved. The unique structure of the composite material promotes the transfer and separation of photogenerated carriers, thereby enhancing the efficiency of photocatalytic reactions.
Article
Chemistry, Applied
Jinrui Zhang, Jie Yin, Wendi Fu, Hongshun Ran, Wei Jiang, Hongping Li, Wenshuai Zhu, Huaming Li, Ming Zhang
Summary: Silica-based porous ionic liquids (OS-PIL) functionalized with quaternary ammonium salt were successfully synthesized to remove dibenzo-thiophene (DBT) in model fuel. The OS-PIL exhibited high extraction activity with a Nernst partition coefficient of 4.22. The synergistic effect between porous materials and ionic liquids, along with the multiple sites in the quaternary ammonium salt, greatly contributed to the high extractive desulfurization efficiency.
FUEL PROCESSING TECHNOLOGY
(2023)
Article
Chemistry, Physical
Armin Raeisi, Alireza Najafi Chermahini, Marzieh Esmaeilzadeh Khabazi, Mohamad Mohsen Momeni, Rafael Luque, Antonio Pineda, Enrique Rodriguez Castellon, Carolina Vargas Fernandez
Summary: This investigation successfully removes sulfur-based compounds by a combination of absorptive and oxidative desulfurization processes using a series of novel Bi-based bifunctional photo electrocatalysts. The results showed that the catalysts had higher efficiency in absorptive desulfurization and better results in oxidative desulfurization. Among the catalysts, photoelectrocatalytic desulfurization performed best in dibenzothiophene removal.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Aparna Deshpande, Shivam Rawat, Indrajit M. Patil, Sunit Rane, Thallada Bhaskar, Satishchandra B. Ogale, Srinivas Hotha
Summary: This study explores saccharide-derived carbons as sustainable anodes for supercapacitors. The acid-base synergistic pre-treatment/activation technique used enhances the surface area and charge storage capacity, thereby improving the performance of the capacitors. The results have important implications for understanding the electrochemical behavior of carbons.
Article
Chemistry, Physical
Maryam Fayazi, Masoud Ghanei-Motlagh
Summary: The PET-AC/Cu(II)-A beads prepared by cross-linking technology showed high adsorption capacity, reusability, and potential as a desulfurization adsorbent for fuels.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Applied
Imteaz Ahmed, Pillaiyar Puthiaraj, Young-Min Chung, Wha-Seung Ahn
Summary: A new cross-linked aromatic porous polymer (CAPP) functionalized with diethyltriamine (DETA) was used as a catalyst for the removal of thiophenic sulfur compounds via oxidative desulfurization. The reaction conditions include temperature range of 80 to 140 degrees C, catalyst amount of 10 to 50 mg, and the catalyst is reusable for four repetitive cycles.
FUEL PROCESSING TECHNOLOGY
(2021)
Review
Chemistry, Multidisciplinary
Qingqing Lu, Kamel Eid, Wenpeng Li
Summary: The rise in CO2 concentration in the Earth's atmosphere is the main cause of environmental issues such as global warming and ocean acidification. Electrochemical CO2 reduction (CO2RR) is a promising green approach to convert CO2 into valuable products. Heteroatom-doped porous carbon-based (HA-PCs) catalysts are considered ideal for CO2RR due to their favorable properties and ability to meet sustainability and large-scale requirements. This review focuses on the rational synthesis of HA-PCs and the impact of dopants on CO2RR activity and durability. It also discusses the effects of CO2 on the environment and human health, recent advances in CO2RR pathways and mechanisms, and the challenges and future perspectives of HA-PCs for CO2RR.
Article
Environmental Sciences
Amin Kazemi-Beydokhti, Hassan Hassanpour-souderjani
Summary: In order to address environmental problems associated with sulfur compounds, various surface modifications of carbon nanostructures were used to effectively remove aromatic sulfur compounds from hydrocarbon fuels. Acid treatment and polymer coating techniques were employed for physical and chemical surface modifications. The results showed that this surface modification significantly improved the removal of impurities from hydrocarbon fuels.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Chemistry, Physical
Xiaoxiao Sun, Dandan Dong, Xiuwen Qiao, Minmin Liu
Summary: Hierarchical N-decorated porous carbons (N-C) were synthesized using N-rich metal-organic framework ZIF-8 as a precursor and dicyandiamide as the secondary nitrogen sources. The synthesized N-C materials showed remarkable adsorption desulfurization capacities. Particularly, the N-C-0.2 sample exhibited high surface areas and a large number of micropores, facilitating rapid mass transfer of organic sulfide molecules. Furthermore, the presence of predominantly excellent graphitic nitrogen content in the N-C materials provided enriched active sites, thereby improving the adsorption desulfurization performance.
MOLECULAR CATALYSIS
(2023)
Article
Chemistry, Physical
Yanqing Wang, Chunshun Yuan, Kunming Li, Dong Li, Anqi Ju
Summary: This study successfully prepared freestanding porous silicon@heteroatom-doped porous carbon fiber by designing a porous structure and adopting heteroatom doping strategy. The material exhibits excellent reversible capacity and cycling stability, indicating its potential application in advanced energy storage.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Environmental Sciences
Xinsheng Li, Shuo Ai, Yongchun Huang, Chengdu Huang, Wanguo Yu, Zhijuan Mao
Summary: In this study, metallic copper loaded on SBA-15 mesoporous silica proved to be an efficient adsorbent for the removal of DBT in fuel oils. Analysis using Raman spectroscopy, XPS, and Auger spectroscopy provided insights into the interaction mechanism between DBT and copper, and the complete recovery of adsorption capacity was achieved successfully.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Biotechnology & Applied Microbiology
Taner Sar, Murat Ozturk, Benjamin C. Stark, Meltem Yesilcimen Akbas
Summary: This study investigated improvements in desulfurization of DBT and DBTS by Paenibacillus strains through immobilization and nanoparticle coating, showing promising results for enhancing biodesulfurization efficiency.
JOURNAL OF APPLIED MICROBIOLOGY
(2022)
Article
Nanoscience & Nanotechnology
Bofeng Zhang, Lirong Zheng, Ziwei Zhai, Guozhu Li, Guozhu Liu
Summary: Propane dehydrogenation (PDH) is a promising technique to produce propylene, but Pt-based catalysts often suffer from stability issues. This study investigated the surface and subsurface composition of supported PtGa nanoparticles and demonstrated that subsurface regulation can enhance propylene selectivity. Furthermore, PtGa alloy nanoparticles encapsulated in MFI zeolite showed enhanced catalytic stability.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Yutong Wang, Siyuan Gong, Hongwang Liu, Guozhu Liu
Summary: In this study, the potential enhancing mechanisms of Pt@FGS nanoparticles in the catalytic decomposition of p-menthane were explored using ReaxFF-MD simulations. The results showed that Pt@FGS nanoparticles exhibited good catalytic reactivity with a reduction of activation energy.
JOURNAL OF PHYSICAL CHEMISTRY A
(2022)
Article
Chemistry, Physical
Bofeng Zhang, Guozhu Li, Sibao Liu, Yucai Qin, Lijuan Song, Li Wang, Xiangwen Zhang, Guozhu Liu
Summary: Metal clusters encapsulated in nanosized zeolites exhibit higher specific activity in propane dehydrogenation due to shorter diffusion length and higher surface permeability, which are achieved by the epitaxial highly crystallized zeolite structure.
Article
Chemistry, Multidisciplinary
Yanjun Li, Shixuan Ren, Guozhu Liu, Zhenxia Liu, Ruifeng Ma
Summary: The TCA-2 coating can inhibit the coking of lubricating oil on the metal surface within a certain temperature range, reduce surface activity, and improve heat resistance. It also shows good compatibility with lubricating oil, effectively reducing the surface temperature of the oil side.
Article
Energy & Fuels
Hongwei Li, Yutong Wang, Li Wang, Xiangwen Zhang, Guozhu Liu
Summary: Under supercritical conditions, decalin can act as a hydrogen donor to suppress coke deposition and promote the pyrolysis and conversion of JP-10, while reducing the formation of polycyclic aromatic hydrocarbons.
Article
Nanoscience & Nanotechnology
Chunyu Zhang, Chan Wu, Li Wang, Guozhu Liu
Summary: The controllable synthesis of specific defective carbon catalysts is essential for the two-electron oxygen reduction reaction (2e- ORR) to generate H2O2. In this study, Mo-CDC-ns, a type of defective carbon catalyst, was successfully prepared by electrochemical activation. The Mo-CDC-ns catalyst exhibited increased kinetic current density and selectivity for H2O2 generation compared to the parent Mo2C/C catalyst, and its defect types were identified as edge defect and vacancy defect sites. Theoretical calculations showed that the defective structure of Mo-CDC-ns had a moderate reaction free energy and smaller energy barrier for 2e- ORR.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Analytical
Baokang Xu, Yutong Wang, Guozhu Liu
Summary: In this study, the reactive force-field molecular dynamics (ReaxFF-MD) simulation was used to investigate the palladium-catalyzed pyrolysis and steam reforming of n-dodecane (n-C12H26). The results showed that pyrolysis reaction supplied C1 and C2 components, and participated in steam reforming to generate aldehyde groups. Compared to catalytic pyrolysis, catalytic steam reforming reduced carbon atoms deposited inside the palladium lattice and improved the heat sink. Furthermore, the proportion of steam reforming increased with more H2O and the contribution of H atoms indicated the variation in the proportion of steam reforming.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2023)
Review
Chemistry, Physical
Junde Wei, Jieyi Liu, Weihao Zeng, Zichen Dong, Jingkuo Song, Sibao Liu, Guozhu Liu
Summary: Plastic waste is a significant environmental threat and economic loss. Catalytic hydroconversion processes have attracted attention for their ability to convert plastic waste into valuable products under mild reaction conditions. This review focuses on recent advances in catalytic hydroconversion processes for converting plastic waste into fuels and chemicals. The review summarizes and exemplifies the hydrocracking and hydrogenolysis of polyolefins, as well as the hydrogenolysis and hydrodeoxygenation of heteroatom-containing plastics. The review also highlights progress in catalyst design, reaction mechanisms, and the impact of key factors on catalytic performance.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Siying Liu, Yajie Tian, Xinyu He, Yong Liu, Congzhen Qiao, Guozhu Liu
Summary: A dual-template method was used to prepare hierarchical ZSM-5 zeolite for catalytic cracking of n-pentane. The synthesized zeolite had adjustable proportions of micropores to mesopores by regulating the content of tetrapropylammonium hydroxide and tetrabutylphosphonium hydroxide. The prepared catalyst exhibited high yield of light olefins and excellent catalytic stability.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Energy & Fuels
Ting Wang, Sibao Liu, Li Wang, Guozhu Liu
Summary: Catalytic steam reforming of toluene was investigated using Rh/CeO2 catalysts prepared by different methods. The Rh/CeO2(LDP-1) catalyst prepared by L-lysine assisted deposition precipitation method exhibited excellent catalytic activity, stability, and resistance to carbon deposition. The superior performance was attributed to the enhanced Rh dispersion, surface Rh0 content, and concentration of surface oxygen vacancy. A dual-site functional catalyst mechanism involving the -CHO group as a key intermediate for gas products generation was proposed. This study highlights the advantages of L-lysine-assisted deposition precipitation method for preparing highly active and stable metal-based catalysts for steam reforming reactions.
Article
Engineering, Chemical
Mingxia Song, Bofeng Zhang, Ziwei Zhai, Sibao Liu, Li Wang, Guozhu Liu
Summary: Atomically dispersed metal catalysts can maximize metal utilization and provide unique chemical properties. Self-pillared nanosheet-supported metal catalysts, such as PtZn/SP-S-1, exhibit high stability and specific activity, with no obvious deactivation after 90 hours at high temperature. They have potential to guide high-temperature catalysis.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Nanoscience & Nanotechnology
Yutong Wang, Guozhu Liu
Summary: This study investigated the mechanism of Pd-Pt alloy catalyst in the dehydrogenation of PHAN using density functional theory. The results showed that PdPt-(111) catalyst had advantages in PHAN dehydrogenation due to lower energy barrier and more stable dehydrogenation products. In addition, a method for selecting the minimum active unit of PdPt catalyst was proposed, and a correlation model among Pd-Pt surface characteristics, catalytic activity, and adsorption energy was established.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Ziwei Zhai, Bofeng Zhang, Yutong Wang, Li Wang, Sibao Liu, Guozhu Liu
Summary: The vacancies and oxygen-containing groups in nanocarbons can enhance the catalytic performance of supported Pt clusters in propane dehydrogenation. In this study, nanocarbons with coexisting vacancies and oxygen-containing groups were designed and their influences on PDH were investigated by density functional theory calculations. Nanocarbons with divacancies and C=O edge groups were found to be the most suitable support for Pt clusters in PDH, resulting in enhanced binding strength and improved stabilization of Pt clusters.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Yutong Wang, Guozhu Liu
Summary: This study provides an atomic-level understanding of the effects of inhomogeneity on reactions in supercritical fluids, using the example of n-decane pyrolysis. The researchers explain the inhomogeneity as the coexistence of gas-like and liquid-like atoms and show that the presence of liquid-like atoms significantly increases the type and frequency of bimolecular reactions, leading to changes in product distributions.
Article
Energy & Fuels
Song Xia, Yulin Zhu, Yajie Tian, Xinyu He, Longhui Guo, Congzhen Qiao, Guozhu Liu
Summary: Fe-Al isomorphous and self-pillared ZSM-5 nanosheets zeolite (Al-Fe-SPZ) with different Fe/Al molar ratios were synthesized by one-pot strategy for catalytic cracking of n-heptane to produce light olefins. Adding Fe into zeolite framework reduced surface acid concentrations and affected the olefins selectivity in catalytic cracking reactions.
JOURNAL OF THE ENERGY INSTITUTE
(2022)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)