Article
Nanoscience & Nanotechnology
Nabin Subedi, Arunas Mesceriakovas, Khai Pham, Anne Heponiemi, Tommi Karhunen, Jarkko J. Saarinen, Ulla Lassi, Anna Lahde
Summary: In this study, a mixed-phase copper on carbon catalyst was produced using spray pyrolysis technique. The synthesis temperature was found to have a significant impact on the physical and chemical properties of the catalyst particles. The catalyst showed excellent photocatalytic activity under both UV and visible light, indicating its potential use in a wider range of the solar spectrum.
Article
Pharmacology & Pharmacy
Saba S. M. Al-Obaidy, Gillian M. Greenway, Vesselin N. Paunov
Summary: An active nanocarrier for chlorhexidine (CHX) based on sterically stabilized shellac nanoparticles with dual surface functionalization has been developed to enhance the antimicrobial action of CHX. Surface modification, encapsulation efficiency, and release kinetics were evaluated for the novel nanocarrier, showing improved antimicrobial effects compared to free CHX on various microorganisms. The enhanced antimicrobial action was attributed to increased electrostatic adhesion between the cationic surface of the nanocarrier and the anionic surface of microorganism cell walls, potentially enabling more efficient formulations in dentistry.
Article
Agricultural Engineering
Kai-Xuan Huang, Ashiwin Vadiveloo, Hua Zhong, Chen Li, Feng Gao
Summary: The study found that CTS@FeBC had significantly higher efficiency in harvesting microalgae compared to BC and FeBC, and it was more effective for harvesting microalgae under acidic and alkaline conditions.
BIORESOURCE TECHNOLOGY
(2023)
Review
Chemistry, Analytical
Andualem Belachew Workie, Henni Setia Ningsih, Shao-Ju Shih
Summary: Nanotechnology involves the study and application of materials, structures, devices, and systems at the nanoscale, which is about one hundred nanometers or smaller. Spray pyrolysis (SP) is a cost-effective method for synthesizing a wide range of nanomaterials, including metals, semiconductors, and ceramics, by decomposing a precursor solution or suspension in a high-temperature environment. There are different types of SP processes, such as tubular reactors and electrostatic spray deposition (ESD), each with unique parameters and requirements. SP has potential applications in fields like nanomedicine, sensing, electrochemical devices, catalysis, and energy conversion and storage, but more research is needed to explore its full potential and develop new applications.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2023)
Article
Agricultural Engineering
Haolian Xu, Hong Wang, Zixuan Liang, Hongbin Chen, Donghai Yang, Zhenzhen Tang, Xiaohu Dai
Summary: This study presents a novel biomimetic flocculation approach using PDADMAC to enhance the harvesting efficiency of microalgae. Compared to conventional methods, this approach minimizes the negative impact on biomass quality.
BIORESOURCE TECHNOLOGY
(2023)
Article
Engineering, Environmental
Luong N. Nguyen, Hang P. Vu, Qiang Fu, Md Abu Hasan Johir, Idris Ibrahim, M. Mofijur, Leen Labeeuw, Mathieu Pernice, Peter J. Ralph, Long D. Nghiem
Summary: This study focuses on the development of flocculants for microalgae harvesting. The synthesized cationic polymers showed excellent flocculation performance for both freshwater and marine microalgae, outperforming commercially available flocculants. The study also established a platform technology for designing and synthesizing cationic flocculants for microalgae harvesting.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Materials Science, Multidisciplinary
Pei-Kai Hsu, Shih-Yun Chen, Ji-Nan Cheng, Jenn-Ming Song, Kiyokazu Yasuda
Summary: Hollow iron submicron spheres with high saturation magnetization were developed through a reductive annealing process, showing optimal performance at a temperature of 425 degrees Celsius.
Article
Green & Sustainable Science & Technology
Yaohui You, Liu Yang, Xubing Sun, Hong Chen, Heng Wang, Nanqiu Wang, Siqin Li
Summary: In this study, a novel tannin-based flocculant (TCCs) was synthesized and successfully grafted onto cationic starch-based flocculants (CCs). Various analyses confirmed the grafting of tannin onto the CCs skeleton. TCCs exhibited excellent harvesting performance at low dosages and had better reflocculation ability. The introduction of tannin allowed TCCs to combine with specific proteins and form compact flocs, leading to dosage savings and improved harvesting efficiency.
JOURNAL OF CLEANER PRODUCTION
(2022)
Review
Energy & Fuels
Ranjit S. Kate, Habib M. Pathan, Ramchandra Kalubarme, Bharat B. Kale, Ramesh J. Deokate
Summary: This paper provides an overview of the research progress on metal oxide thin films for supercapacitor applications. The spray pyrolysis technique is used to deposit these films, which have high energy and power density, making them important for energy storage. The films have a large surface area and appropriate pore size distribution due to the nanostructured metal oxides, resulting in high specific capacitance and improved performance.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Polymer Science
Roberta S. Pugina, Douglas L. da Silva, Andre Riul, Manoel L. da Silva-Neto, Anderson S. L. Gomes, Jose Mauricio A. Caiut
Summary: This study investigated the preparation and characteristics of a new fibroin composite enhanced by YAG particles, successfully achieving controlled particle amounts and tuned transmittance behavior, providing a new approach for the development of sensors or smart inks.
Article
Chemistry, Multidisciplinary
Javier Zamudio-Garcia, Leire Caizan-Juanarena, Jose M. Porras-Vazquez, Enrique R. Losilla, David Marrero-Lopez
Summary: This study investigates the influence of different electrolytes on the electrochemical performance of LSCF nanostructured electrodes. The results show that the ionic conductivity of the electrolyte has a significant impact on the polarization resistance of LSCF. Additionally, the rate-limiting steps for the oxygen reduction reaction (ORR) remain the same regardless of the electrolyte used.
Review
Energy & Fuels
Jianping Chen, Zan Zhu, Wei-Ning Wang
Summary: This article reviews a rapid microdroplet-based nanomanufacturing process to fabricate MOFs-based functional materials with controlled hierarchical nanostructures. Strategies to integrate MOFs with semiconductors to form hybrid photocatalysts for addressing environmental challenges, particularly CO2 photoreduction, are summarized. In-situ techniques were used to explore the quantitative mechanisms of CO2 adsorption, activation, and charge transfer within the hybrid nanostructures.
JOURNAL OF PHYSICS-ENERGY
(2021)
Article
Engineering, Environmental
Shuo Liu, Mohammad Moein Mohammadi, Mark T. Swihart
Summary: This review provides an overview of flame aerosol synthesis of catalysts, including the mechanisms, applications, and recent progress. By controlling process parameters and reactor configuration, catalyst structures can be tailored. The advantages, limitations, and future research directions of flame-made catalysts are also discussed in the review.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Chemical
Qijia Cai, Kezheng Song, Pei Cai, Cuicui Tian, Chunbo Wang, Bangding Xiao
Summary: Cationic polyacrylamide (CPAM) effectively harvests cyanobacteria with low dosages, but its effectiveness is limited for some green algae due to the lack of high molecular weight and negatively charged extracellular organic matter (EOM) components. High molecular weight and negative charge density of EOM are crucial factors for successful retention of microalgae.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Chemical
Georgia Kastrinaki, Margaritis Kostoglou, Athanasios G. Konstandopoulos
Summary: Stringent regulation is put in place to restrict global vehicle emissions, with advanced catalytic systems incorporating expensive platinum group metals for oxidation catalysis. In this study, porous silica and alumina particles doped with Pt, Ce, and Na were synthesized and evaluated for their pore size distribution. The evaluation showed that samples with higher surface areas exhibited higher conversion curves for NO oxidation, indicating the importance of surface area in the oxidation kinetics. Additionally, the study also explored the correlation between reactant accessibility to in-pore Pt nanoparticles and catalytic activity using a reaction kinetic model.
CHEMICAL ENGINEERING SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Jeong-Cheol Seo, Hyunjoung Kim, Yeol-Lim Lee, Sungchan Nam, Hyun-Seog Roh, Kyubock Lee, Seung Bin Park
Summary: This study successfully prepared mesoporous supported nickel catalysts with high activity and stability in DRM reaction through a one-pot synthesis method. By using spray pyrolysis-assisted evaporation-induced self-assembly, the catalysts with highly dispersed nickel active sites were obtained in one step. Furthermore, the performance of nickel catalysts was further optimized by employing phase segregation and exsolution strategies.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Nanoscience & Nanotechnology
Bon-Jun Ku, Byoung-Min Lee, Dong Hyun Kim, Anush Mnoyan, Sung-Kwon Hong, Kang Seok Go, Eun Hee Kwon, Shin-Hyun Kim, Jae-Hak Choi, Kyubock Lee
Summary: The new concept of SEOA combining solar-driven evaporation and adsorption is proposed for efficient oil-spill remediation. The photothermal fabrics significantly enhance oil removal, removing 95% of the crude oil in experiments. This approach shows potential for minimizing environmental disaster through fast and efficient oil-spill remediation.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Hana-Nur Fitriana, Soo-Youn Lee, Sun-A Choi, Ji-Ye Lee, Bo-Lam Kim, Jin-Suk Lee, You-Kwan Oh
Summary: This study investigated the technical feasibility of inducing astaxanthin biosynthesis in H. pluvialis using electric stimulation in a two-chamber bioelectrochemical system. An optimal voltage of 4 V (anodic current: 30 mA) effectively stimulated astaxanthin biosynthesis, resulting in a 36.9% increase in astaxanthin content in treated cells compared to untreated cells. Proper regulation of bioelectrochemical parameters can improve astaxanthin production in H. pluvialis culture using electric treatment.
APPLIED SCIENCES-BASEL
(2021)
Review
Environmental Sciences
Ana Rotter, Michele Barbier, Francesco Bertoni, Atle M. Bones, M. Leonor Cancela, Jens Carlsson, Maria F. Carvalho, Marta Ceglowska, Jeronimo Chirivella-Martorell, Meltem Conk Dalay, Mercedes Cueto, Thanos Dailianis, Irem Deniz, Ana R. Diaz-Marrero, Dragana Drakulovic, Arita Dubnika, Christine Edwards, Hjoerleifur Einarsson, Aysegul Erdogan, Orhan Tufan Eroldogan, David Ezra, Stefano Fazi, Richard J. FitzGerald, Laura M. Gargan, Susana P. Gaudencio, Marija Gligora Udovic, Nadica Ivosevic DeNardis, Rosa Jonsdottir, Marija Katarzyte, Katja Klun, Jonne Kotta, Leila Ktari, Zrinka Ljubesic, Lada Lukic Bilela, Manolis Mandalakis, Alexia Massa-Gallucci, Inga Matijosyte, Hanna Mazur-Marzec, Mohamed Mehiri, Soren Laurentius Nielsen, Lucie Novoveska, Donata Overlinge, Giuseppe Perale, Praveen Ramasamy, Celine Rebours, Thorsten Reinsch, Fernando Reyes, Baruch Rinkevich, Johan Robbens, Eric Roettinger, Vita Rudovica, Jerica Sabotid, Ivo Safarik, Siret Talve, Deniz Tasdemir, Xenia Theodotou Schneider, Olivier P. Thomas, Anna Torunska-Sitarz, Giovanna Cristina Varese, Marlen Vasquez
Summary: Coastal countries have traditionally relied on marine resources for various needs, while modern societies have increased demands for diverse products leading to the emergence of blue biotechnology. This field offers opportunities for commercial interests in pharmaceuticals, cosmetics, food, and related industries. Exploration of marine resources and their potential applications in various sectors are highlighted, along with the importance of legislation, funding, communication, and stakeholder engagement in the development of marine biotechnology.
FRONTIERS IN MARINE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Hana Nur Fitriana, Jiye Lee, Sangmin Lee, Myounghoon Moon, Yu Rim Lee, You-Kwan Oh, Myeonghwa Park, Jin-Suk Lee, Jinju Song, Soo Youn Lee
Summary: This study utilized an electroactive bacterium Rhodobacter sphaeroides for microbial electrosynthesis, enhancing the efficiency of CO2 reduction reaction and achieving higher yields by modifying the cathode material.
APPLIED SCIENCES-BASEL
(2021)
Article
Chemistry, Multidisciplinary
Nakyeong Lee, Aditya Lakshmi Narasimhan, Gyuseop Moon, Young-Eun Kim, Myeonghwa Park, Bolam Kim, Rendi Mahadi, Sungwook Chung, You-Kwan Oh
Summary: This study explores the technical feasibility of room-temperature extraction of astaxanthin using a combination of ultrathin alpha-quartz nanoplates (NPLs) and ionic liquids (ILs). The results show that NPLs can effectively disrupt the cell wall of cysts, thereby improving the extraction efficiency of astaxanthin.
APPLIED SCIENCES-BASEL
(2022)
Article
Chemistry, Multidisciplinary
Rendi Mahadi, Laxmi Priya Sathiya Vahisan, Dea Prianka Ayu Ilhamsyah, Sangui Kim, Bolam Kim, Nakyeong Lee, You-Kwan Oh
Summary: The effects of a phytohormone rac-GR24 on the growth and biosynthesis of astaxanthin and fatty acids in Haematococcus pluvialis were investigated. The results showed that the addition of rac-GR24 at an appropriate concentration improved biomass production and the production of astaxanthin and fatty acids.
APPLIED SCIENCES-BASEL
(2022)
Article
Chemistry, Physical
Seung Bo Kim, Ahmed Al-Shahat Eissa, Min-Jae Kim, Emad S. Goda, Jae-Rang Youn, Kyubock Lee
Summary: A facile and green synthetic strategy was developed to construct an efficient Ni@CeO2 catalyst for the dry reforming of methane. The catalyst showed superb syngas production efficiency and stability, with resistance to carbon deposits and sintering. It exhibited high catalytic activity and durability during the DRM reaction.
Article
Environmental Sciences
Amalie Thit, Sara Nicoline Gronlund, Louise Lynn Trudso, Benni Winding Hansen, Simon David Herzog, Soren Laurentius Nielsen, Nikoline Garner Oturai, Dorthe Posselt, Praveen Kumar Ramasamy, Monica Hamann Sandgaard, Kristian Syberg, Henriette Selck, Gry Lyngsie
Summary: This study investigated the interactions, transport, and fundamental concepts of particles and their associated co-transported matter (CTM) in the aquatic environment. The researchers emphasize the importance of understanding the transport of particle-associated CTM and the assumptions in generic models. They also highlight the need for interdisciplinary collaborations and a consistent terminology to foster progress in research on anthropogenic carrier particles.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Chemistry, Physical
Mamoona Waris, Howon Ra, Sungmin Yoon, Min-Jae Kim, Kyubock Lee
Summary: This study investigates the effect of citric acid concentration on the preparation of highly dispersed Ni catalysts on mesoporous silica for the dry reforming of methane. The addition of citric acid during catalyst synthesis results in highly dispersed Ni particles and improves catalytic performance. However, too high of a citric acid concentration leads to the formation of larger Ni particles.
Article
Agricultural Engineering
Mikyoung Jung, Young-Eun Kim, Nakyeong Lee, Hyoji Yu, Jiye Lee, Soo Youn Lee, Young-Chul Lee, You-Kwan Oh
Summary: Magnesium aminoclay nanoparticles (MgANs) have both positive and negative effects on photosynthetic microalgae. This study investigated the use of MgANs in producing algal lipids under high CO2 concentrations. Among three oleaginous Chlorella strains, only KR-1 showed significant improvement in lipid content and extraction efficiency in the presence of MgANs. This improvement was due to increased biosynthesis of triacylglycerols and a thinner cell wall.
BIORESOURCE TECHNOLOGY
(2023)
Article
Engineering, Environmental
Siranuysh Badalyan, Anush Mnoyan, Alexey Sobolev, Iana S. Soboleva, Igor A. Presniakov, Jae-Rang Youn, Taeyoul Han, Dongyeon Kim, Kyubock Lee
Summary: Iron saccharide complexes based on sucrose and fructose ligands are reported as efficient electrocatalysts for electrochemical nitric oxide reduction reaction (e-NORR) at ambient conditions, showing high efficiency and stability.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Applied
Dong Hyun Kim, Jeong-Cheol Seo, Yong Jun Kim, Jeongmin Kim, Sungmin Yoon, Howon Ra, Min-Jae Kim, Kyubock Lee
Summary: This study developed a series of Ni-Co alloy catalysts using the exsolution method and explored the optimal Ni/Co ratio for dry reforming methane (DRM) reaction. The catalysts exhibited improved activation balance in methane and carbon dioxide, excellent coking resistance, and reaction pathway efficiency by incorporating Co as a secondary metal and precisely controlling its proportion. The Ni4Co1 catalyst showed excellent coke resistance with the lowest coking rate of only 0.34% compared to the monometallic Ni catalyst. The findings of this study provide insights into the fabrication of high-performance DRM catalysts utilizing the exsolution-driven alloying technique.
Article
Engineering, Environmental
Jeong-Cheol Seo, Eunkyung Cho, Jeongmin Kim, Seung Bo Kim, Jae-Rang Youn, Dong Hyun Kim, Praveen Kumar Ramasamy, Kyubock Lee, Chang Hyun Ko
Summary: Doping strontium in nickel-supported alumina catalysts significantly enhances coke resistance, while doping with different basic metals like magnesium, calcium, strontium, barium, and lanthanum improves the thermal stability of the catalysts for maintaining long-term reaction stability.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Hyunjoung Kim, Ahmed Al-Shahat Eissa, Seung Bo Kim, Hongjin Lee, Woohyun Kim, Dong Joo Seo, Kyubock Lee, Wang Lai Yoon
Summary: The newly synthesized mesoporous Ni/MgAl2O4 spinel catalyst exhibits high efficiency and durability in steam methane reforming reaction, with superb resistance to carbon deposition. The catalyst's structure and catalytic activity can be tuned by controlling annealing conditions.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)