期刊
MOLECULAR DIVERSITY
卷 20, 期 2, 页码 567-573出版社
SPRINGER
DOI: 10.1007/s11030-016-9657-z
关键词
alpha-Aminoxylated dicarbonyl compounds; Quinoxaline; Pyrazine; Pyridopyrazine; Benzoxazin-2-one
类别
资金
- Henan Province [2013039]
- National students' innovation and entrepreneurship training program [201310472019]
Simple and efficient synthetic procedures for the preparation of quinoxaline, pyrazine, pyridopyrazine, and benzoxazin-2-one derivatives were developed. The one-pot cascade process involves the acidic elimination of -aminoxylated dicarbonyl compounds to generate 1,2,3-tricarbonyl compounds and subsequent condensation with 1,4-N,N or -N,O dinucleophiles to afford quinoxaline, pyrazine, pyridopyrazine, and benzoxazin-2-one scaffolds. All the proposed processes do not need extra catalysts, dry solvents, or harsh reaction conditions.
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