Article
Multidisciplinary Sciences
N. A. Kotb, M. S. Abd El Ghany, Ashraf A. El-sayed
Summary: In this study, the radiological assessment of monazite in Egyptian black sands was conducted, and the associated hazard indices were calculated. The results showed that the radioactivity of the monazite samples exceeded the recommended limits, indicating potential hazards of ionizing radiation. Therefore, radiation safety measures are necessary.
SCIENTIFIC REPORTS
(2023)
Article
Food Science & Technology
F. Pinero-Garcia, R. Thomas, J. Mantero, E. Forssell-Aronsson, M. Isaksson
Summary: The entrance of radionuclides into the human food chain can have long-term implications for radiation doses, affecting world population. Monitoring and analyzing food is necessary to control and quantify the risk of exposure to the public.
Article
Food Science & Technology
F. Pinero-Garcia, R. Thomas, J. Mantero, E. Forssell-Aronsson, M. Isaksson
Summary: The study found that some brands of bottled water in the Swedish market exceeded the drinking water standard in terms of radioactive isotope content, primarily due to high activity concentrations of 238U, 234U, 210Po, and 210Pb.
Article
Chemistry, Analytical
M. Laassiri, H. Ait Bouh, N. Ziad, J. Naouli, A. Laissaoui
Summary: In this study, gross alpha and gross beta activities in 14 bottled mineral waters in Morocco were measured following ISO 11704:2018 standard. The method was verified and confirmed its performance parameters in the laboratory. The gross alpha and gross beta activities ranged from minimum < DL (below detection limit) to maximum 0.211 +/- 0.015 and 0.151 +/- 0.008 Bq L-1 respectively. No significant correlation was found between activities and total dissolved salts (TDS) contents, which ranged from 141 to 2078 mg L-1.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
(2023)
Article
Biochemistry & Molecular Biology
Meng Cao, Qin Peng, Yue Wang, Guangsheng Luo, Lijuan Feng, Shilei Zhao, Yihui Yuan, Ning Wang
Summary: Utilization of uranium resource in seawater can meet the growth demands for nuclear energy industry. A low-cost soy protein isolate is used to fabricate adsorbent named SPI hydrogel for uranium extraction, achieving high uranium adsorption capacity in simulated nuclear wastewater and natural seawater. The functional groups, amino and oxygen-containing groups, provide high binding selectivity and affinity to uranyl ions.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Physical
Qixuan Lin, Qiwen Zhan, Yue Wu, Jianlin Wang, Libo Li, Feng Xu, Feng Xu, Junli Ren
Summary: This study investigates the molecular behavior of xylan-type hemicellulose during solvent-controlled extraction and precipitation using molecular dynamics simulations and density functional theory calculations. The study explains four phenomena at the molecular level and contributes to an increased understanding of the dissolution and precipitation mechanisms of hemicellulose. It provides a theoretical basis for the efficient extraction of high-purity hemicellulose.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Engineering, Environmental
Yutao Zhang, Ruzhen Zhao, Xiaohuan Zhang, Qifeng Wei, Xiulian Ren, Ziwen Ying
Summary: In this study, a novel and cleaner production process was developed to remove impurity anions by precipitation and purify vanadium by solvent extraction using an ionic liquid. The optimized precipitation process effectively removed most of the impurity anions. The vanadium extraction and stripping efficiency reached high levels, resulting in obtaining V2O5 product with a purity of over 99.8%. The extraction mechanism of vanadium (V) with the ionic liquid was investigated in-depth and the essence of the extraction process was explained at the molecular level.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2023)
Article
Chemistry, Analytical
Ghada G. El-Gamal, Wael I. Mortada, Mohamed M. Hassanien, Amr A. Ibrahim, Yasmeen G. Abou El-Reash
Summary: This article presents a new method for the separation of thorium ions using Morin to form a stable complex in an acidic medium, combined with SFODME technology. Under optimized conditions, the method showed low detection limits, good reproducibility, and successful application in phosphate rock and ceramic tile samples.
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2021)
Article
Chemistry, Analytical
M. Lunardi, D. M. Bonotto
Summary: Hot springs from the Caldas Novas Thermal Complex have been analyzed for their natural radioactivity, particularly in relation to dissolved Rn-222, U-238, and U-234. The study observed the impact of seasonal variations on these radioelements by conducting sampling campaigns during both dry and rainy seasons. The results revealed significant correlations between various factors, such as Rn-222 with dissolved oxygen, Eh, and sodium, and U-238 with dissolved oxygen, pH, electrical conductivity, and calcium. The U-234/U-238 activity ratio was used to identify potential uranium ore bodies and to understand groundwater mixing processes in the area.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
(2023)
Article
Chemistry, Analytical
Ahad Ghaemi, Alireza Hemmati
Summary: Optimization of influential factors in uranium extraction from nuclear waste using Tri-butyl-phosphate extractant led to increased extraction efficiency. Phosphoric acid was selected as the most suitable option with an extraction efficiency of 76%.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
(2021)
Article
Metallurgy & Metallurgical Engineering
S. M. Masloboeva, L. G. Arutyunyan, M. N. Palatnikov, D. V. Manukovskaya
Summary: High recovery rates of tantalum and niobium were achieved by leaching a plumbomicrolite concentrate with mixtures of HF and H2SO4, HF and HNO3 acids. The use of fluoride-sulfuric acid and fluoride-nitric acid schemes, along with extractive separation techniques, led to the production of high-purity tantalum compounds that meet impurity content standards. The profitability of the processing scheme ultimately determines the final choice for PMC treatment.
JOURNAL OF CENTRAL SOUTH UNIVERSITY
(2021)
Article
Metallurgy & Metallurgical Engineering
Moheddine Wehbie, Guilhem Arrachart, Tamir Sukhbaatar, Xavier F. Le Goff, Iyad Karame, Stephane Pellet-Rostaing
Summary: The newly synthesized extractants showed higher efficiency in extracting uranium from sulfate media, with successful quantitative recovery of uranium after extraction.
Article
Engineering, Environmental
Carmen A. Velasco, Adrian J. Brearley, Jorge Gonzalez-Estrella, Abdul-Mehdi S. Ali, Maria Isabel Meza, Stephen E. Cabaniss, Bruce M. Thomson, Tori Z. Forbes, Juan S. Lezama Pacheco, Jose M. Cerrato
Summary: The study found that natural organic matter (NOM) promotes the precipitation of U(VI) at low pH, which could be relevant to the formation of mineral deposits, radioactive waste repositories, wetlands, and other U- and organic-rich environmental systems. Adsorption and precipitation of U(VI) in the presence of NOM occur at pH 2 and pH 4, while aqueous complexation of U by dissolved organic matter is favored at pH 7, preventing its precipitation. Spectroscopic analyses showed that U(VI) is mainly adsorbed to particulate organic matter at pH 4, but electron microscopy identified U(VI)-bearing ultrafine to nanocrystalline solids at pH 4.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2021)
Article
Biochemistry & Molecular Biology
Julie Durain, Damien Bourgeois, Murielle Bertrand, Daniel Meyer
Summary: The study introduces an alternative liquid/liquid extraction method based on TBP for the efficient separation of uranium and thorium. Proof of concept has been established, including two control methods: addition of concentrated nitric acid or temperature drop. Successful metal and solvent recovery has also been demonstrated.
Article
Environmental Sciences
D. E. Tchorz-Trzeciakiewicz, M. Rysiukiewicz
Summary: The study aimed to analyze the usefulness of ambient gamma dose rate survey in assessing radon concentration in the environment and geogenic radon potential. The results showed a significant correlation between ambient gamma dose rate and radon concentrations in soil and atmosphere, indicating that ambient gamma dose rate can be a useful parameter to indicate geogenic radon potential.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)