Ammonia-induced construction of three-dimensional sea urchin-like Co (OH)2 @CuO structure for oxygen evolution reaction and supercapacitor

The development of low-cost and earth-abundant electrocatalysts with efficient energy conversion and excellent super-capacitive storage is highly desirable for practical applications. Herein, three-dimensional sea urchin-like Co(OH)2 @CuO structure nanocomposites were successfully synthesized by an ammonia coordination strategy. Compared with Co(OH)2 and CuO electrocatalysts, the optimized Co(OH)2 @CuO composite exhibits excellent oxygen evolution reaction activity and supercapacitor performance due to the synergistic effect between them. The as-prepared Co(OH)2 @CuO-2 electrocatalyst displays a low overpotential of 361 mV to drive 10 mA cm-2 and a long-term durability during at least 30 h of OER testing. In addition, Co(OH)2 @CuO-2 also exhibits a high capacitance of 270.8 F g-1 at 0.5 A g-1 when used as a supercapacitor electrode. This work provides a new idea for developing highly active, low-cost bifunctional electrocatalysts for electrochemical conversion and energy storage. & COPY; 2023 Elsevier B.V. All rights reserved.

Automated summary

Three-dimensional sea urchin-like Co(OH)2 @ CuO nanocomposites were synthesized by an ammonia coordination strategy. The optimized Co(OH)2 @ CuO composite exhibited excellent oxygen evolution reaction activity and supercapacitor performance due to the synergistic effect between Co(OH)2 and CuO. It also showed a long-term durability and high capacitance when used as a supercapacitor electrode.