期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 9, 页码 1605-1607出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07978g
关键词
-
资金
- Chinese National Natural Science Foundation [21173178, 21232005, 21375113]
- National Basic Research Program of China [2012CB821600]
- Program for Changjiang Scholars and Innovative Research Team in University
A new, general method for the synthesis of phosphono-gamma-butyrolactones has been achieved through Mn(OAc)(3)-mediated radical oxidative phosphonation and lactonization of alkenoic acids with H-phosphonates and H-phosphine oxide. Mn(OAc)(3) can be readily prepared from Mn(OAc)(2) in the laboratory. This transformation allows the direct formation of a P-C bond and the construction of a lactone ring in one reaction.
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