期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 6, 页码 1077-1080出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08467e
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资金
- National Natural Science Foundation of China [21103174, 21233008]
- Strategic Priority Research Program-Climate Change: Carbon Budget and Related Issues of the Chinese Academy of Sciences [XDA05010203]
An excellent linear correlation between ln delta (OH chemical shift) and 1/T (temperature) is discovered for the first time for hydroxyl compounds. The derived slope (A) provides information as an index not only for distinguishing different types of H-bonds, but also for predicting their reactivities. This finding can be extended to other H-bond-containing molecules.
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