Rh(iii)- or Ir(iii)-catalyzed ynone synthesis from aldehydes via chelation-assisted C–H bond activation

Iridium(III)-Catalyzed C-7 Selective C–H Alkynylation of Indolines at Room Temperature

(2015) Yunxiang Wu et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium- and Rhodium-Catalyzed C–H Activation and Formyl Alkynylation of Benzaldehydes under Chelation-Assistance

(2015) He Wang et al.   ORGANIC LETTERS

Rhodium-Catalyzed CH Alkynylation of Arenes at Room Temperature

(2014) Chao Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of conjugated 1,3-enynes by Rh(iii)-catalysed alkynylation of alkenes via C–H activation

(2014) Karl D. Collins et al.   CHEMICAL COMMUNICATIONS

RhIII-Catalyzed Hydroacylation Reactions betweenN-Sulfonyl 2-Aminobenzaldehydes and Olefins

(2014) Tao Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Intramolecular Redox-Neutral Annulation of Tethered Alkynes: Formal Total Synthesis of (±)-Goniomitine

(2014) Bing Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

A General Synthesis of Ynones from Aldehydes via Oxidative C–C bond Cleavage under Aerobic Conditions

(2014) Zhaofeng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)- and Ir(III)-Catalyzed C–H Alkynylation of Arenes under Chelation Assistance

(2014) Fang Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(iii)-catalyzed coupling of N-sulfonyl 2-aminobenzaldehydes with oxygenated allylic olefins through C–H activation

(2014) Tingting Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh(III)-Catalyzed Intramolecular Redox-Neutral or Oxidative Cyclization of Alkynes: Short, Efficient Synthesis of 3,4-Fused Indole Skeletons

(2014) Bing Zhou et al.   ORGANIC LETTERS

Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Bromides Using Near Stoichiometric Carbon Monoxide

(2014) Karoline T. Neumann et al.   ORGANIC LETTERS

Gold(I)-Catalyzed Diastereoselective Hydroacylation of Terminal Alkynes with Glyoxals

(2013) Shuai Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dehydrogenative Meyer-Schuster-Like Rearrangement: A Gold-Catalyzed Reaction Generating an Alkyne

(2013) Yang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Regioselective Synthesis of 2- and 3-Alkynyl Furans

(2013) Yifan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium catalyzed oxidative coupling of salicylaldehydes with diazabicyclic olefins: a one pot strategy involving aldehyde C–H cleavage and π-allyl chemistry towards the synthesis of fused ring chromanones

(2013) E. Jijy et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Directed Sulfenylation of Arene CH Bonds

(2013) Yaxi Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Amidation of Aryl KetoneO-Methyl Oximes with Isocyanates by CH Activation: Convergent Synthesis of 3-Methyleneisoindolin-1-ones

(2013) Bing Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Synthesis of Amides from Aldehydes and Azides by Chelation-Assisted CH Bond Activation

(2013) Bing Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium-Catalyzed Intramolecular Hydrocarbamoylation of Allylic Formamides: Convenient Access to Chiral Pyrrolidones

(2013) Nicolas Armanino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Rhodium-Catalyzed Direct Addition of Aryl C–H Bonds to Nitrosobenzenes at Room Temperature

(2013) Bing Zhou et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Intermolecular Direct Amidation of Aldehyde C–H Bonds with N-Chloroamines at Room Temperature

(2013) Bing Zhou et al.   ORGANIC LETTERS

Metal-Free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

(2013) Cassandra Taylor et al.   ORGANIC LETTERS

Rh(III)-Catalyzed C–H Amidation with N-Hydroxycarbamates: A New Entry to N-Carbamate-Protected Arylamines

(2013) Bing Zhou et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Dehydrogenative Heck Reaction of Salicylaldehydes

(2012) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Electrophilic alkynylation: the dark side of acetylene chemistry

(2012) Jonathan P. Brand et al.   CHEMICAL SOCIETY REVIEWS

Intermolecular Hydroacylation: High Activity Rhodium Catalysts Containing Small-Bite-Angle Diphosphine Ligands

(2012) Adrian B. Chaplin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Phosphoramidite Catalyzed Alkene Hydroacylation: Mechanism and Octaketide Natural Product Synthesis

(2012) Max von Delius et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Ynone Trifluoroborates toward Functionalized Pyrazoles

(2012) James D. Kirkham et al.   ORGANIC LETTERS

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Syntheses of N-Heterocyclic Ynones and Ynediones by In Situ Activation of Carboxylic Acids with Oxalyl Chloride

(2011) Christina Boersch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of Frustrated Lewis Pairs with Conjugated Ynones-Selective Hydrogenation of the Carbon-Carbon Triple Bond

(2011) Bao-Hua Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Palladium-catalyzed direct oxidative Heck–Cassar–Sonogashira type alkynylation of indoles with alkynes under oxygen

(2010) Luo Yang et al.   CHEMICAL COMMUNICATIONS

A General and Convenient Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Bromides

(2010) Xiao-Feng Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regio- and Enantioselective Intermolecular Hydroacylation: Substrate-Directed Addition of Salicylaldehydes to Homoallylic Sulfides

(2010) Matthew M. Coulter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Synthesis of Quinazolines through Copper-Catalyzed Reaction of Aniline-Derived Benzamidines

(2010) Yusuke Ohta et al.   ORGANIC LETTERS

Highly Efficient and Versatile Pd-Catalyzed Direct Alkynylation of Both Azoles and Azolines

(2010) Seok Hwan Kim et al.   ORGANIC LETTERS

Combined Rhodium-Catalyzed Carbon-Hydrogen Activation and β-Carbon Elimination to access Eight-Membered Rings

(2009) Damien Crépin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Alkynylation of Indole and Pyrrole Heterocycles

(2009) Jonathan P. Brand et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal Catalyzed Alkene and Alkyne Hydroacylation

(2009) Michael C. Willis   CHEMICAL REVIEWS

An Improved Synthesis of Pyridine−Thiazole Cores of Thiopeptide Antibiotics

(2009) Virender S. Aulakh et al.   JOURNAL OF ORGANIC CHEMISTRY

Hydrocarbamoylation of Unsaturated Bonds by Nickel/Lewis-Acid Catalysis

(2009) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Intramolecular Acylation of Aryl Bromides via C−H Functionalization: A Highly Efficient Synthesis of Benzocyclobutenones

(2009) Paula Álvarez-Bercedo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Access to Flavones via a Microwave-Assisted, One-Pot Sonogashira−Carbonylation−Annulation Reaction

(2009) Emelia Awuah et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct Alkynylation of C−H Bonds in Benzenes

(2009) Mamoru Tobisu et al.   ORGANIC LETTERS

Chemistry of Polyvalent Iodine

(2008) Viktor V. Zhdankin et al.   CHEMICAL REVIEWS

Three-Component Synthesis of Cryofluorescent 2,4-Disubstituted 3H-1,5-Benzodiazepines - Conformational Control of ­Emission Properties

(2008) Benjamin Willy et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rh-Catalyzed Carbonyl Hydroacylation:  An Enantioselective Approach to Lactones

(2008) Zengming Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Intermolecular Hydroacylation: Rhodium-Catalyzed Combination of β-S-Aldehydes and 1,3-Disubstituted Allenes

(2008) James D. Osborne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic alkynone generation by Sonogashira reaction and its application in three-component pyrimidine synthesis

(2008) Daniel M D'Souza et al.   Nature Protocols