☆ 4.7 Article

Solvent-dependent strong asymmetric amplification in the catalytic enantioselective Henry reaction using the trans-N,N′-bis-biphenyl-4-ylmethyl-cyclohexane-1,2-diamine-CuCl2 complex

CHEMICAL COMMUNICATIONS (2015)

期刊

CHEMICAL COMMUNICATIONS

卷 51, 期 37, 页码 7907-7910

出版社

ROYAL SOC CHEMISTRY

DOI: 10.1039/c5cc02302e

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Chemistry, Multidisciplinary

资金

Kansai University Special Research Fund
Grants-in-Aid for Scientific Research [26410126] Funding Source: KAKEN

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摘要

A strong asymmetric amplification was observed in the enantioselective Henry reaction catalyzed by the (R,R)-trans-N,N'-bis-biphenyl-4-ylmethyl-cyclohexane-1,2-diamine center dot CuCl2 complex in AcOEt, while no amplification occurred in MeOH.

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