期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 27, 页码 5925-5928出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10155c
关键词
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资金
- National Natural Science Foundation of China [21202138]
- Xiangtan University Academic Leader Program'' [11QDZ20]
- Ministry of Education [20124301120007]
- Hunan Provincial Natural Science Foundation [13JJ4047, 12JJ7002]
- Hunan Provincial Excellent Young Scientist Foundation [13B114]
- New Teachers' Fund for Doctor Stations
A metal-free oxidative decarbonylative coupling of aromatic aldehydes with electron-rich or electron-deficient arenes to produce biaryl compounds was developed. This novel coupling was proposed to proceed via a non-chain radical homolytic aromatic substitution (HAS) type mechanism, based on the substrate scope, ortho-regioselectivity, radical trapping experiments and DFT calculation studies. With the ready availability of aromatic aldehydes and arenes, metal-free conditions should make this coupling attractive for the biaryl synthesis.
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