期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 5, 页码 855-857出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08426h
关键词
-
资金
- JSPS [220GR049]
- MEXT [25105720, 25708005]
- International Research Training Group Munster/Nagoya
- World Premier International Research Center (WPI) Initiative, Japan
- Grants-in-Aid for Scientific Research [25105720, 25708005] Funding Source: KAKEN
A nickel-catalyzed alpha-arylation of esters and amides with phenol derivatives has been accomplished. In the presence of our unique nickel catalyst, prepared in situ from Ni(cod)(2), 3,4-bis(dicyclohexyl-phosphino) thiophene (dcypt), and K3PO4, various esters and amides undergo alpha-arylation with O-arylpivalates or O-arylcarbamates to afford the corresponding coupling products. The thus obtained alpha-aryl esters and amides are useful precursors of privileged motifs such as alpha-arylcarboxylic acids and beta-arylamines.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据