期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 54, 页码 10907-10909出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01932j
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资金
- University of Heidelberg
- State of Baden-Wurttemberg
- BASF SE
- German Federal Ministry for Education and Research (BMBF) [01RC1015A]
We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.
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