期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 21, 页码 4433-4436出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08830a
关键词
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资金
- NBRPC [2013CB934302]
- NSFC [21222301, 21171170]
- MHRSSC
- CAS/SAFEA International Partnership Program for Creative Research Teams
- Hundred Talents Program of the Chinese Academy of Sciences
- Air Force Office of Scientific Research under AFOSR Award [FA9550-11-1-0147]
- Camille Dreyfus Teacher-Scholar Awards Program
A new nanocluster of atomic precision, Au-44(SC2H4Ph)(32), is obtained by an oxidation-decomposition-recombination (ODR) process from Au-25(SC2H4Ph)(18) under mild conditions with high yield (75%). Among the investigated gold nanoclusters, Au-44(SC2H4Ph)(32) exhibits the highest catalytic activity for the reduction of 4-nitrophenol, especially at low temperature, indicating that the catalytic properties of gold nanoclusters are not only size-dependent, but also structure-sensitive.
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