期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 30, 页码 6625-6628出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01287b
关键词
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Cu-catalyzed oxidative Povarov reactions between N,N-dialkylanilines and saturated oxa- or thiacycles with tert-butyl hydroperoxide (TBHP) are described; notably, the reactions use neither [4 pi] nor [2 pi]-motifs as the initial reagents. The use of cheap alkane-based substances as building units is of mechanistic and practical interest as two inert sp(3) C-H bonds are activated.
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