期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 5, 页码 839-842出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08003c
关键词
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资金
- 973 Program [2012CB821705, 2013CB933800]
- NSFC [21271120, 21475078, 21101100]
- Shangdong Natural Science Foundation [BS2012CL035]
- Taishan scholar's construction project
A porous Ni(II)-MOF, which was constructed from a new bent fluorene-bridged ligand and NiCl2 under solvothermal conditions, can reversibly uptake organic solvent molecules and iodine species in a single-crystal-to-single-crystal (SC-SC) fashion. Furthermore, the obtained I-2 subset of Ni(II)-MOF can be a highly active heterogeneous catalyst to promote solvent-free silylcyanation of aromatic aldehydes under mild conditions.
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