4.7 Article

New insights into the oxidative dehydrogenation of propane on borate-modified nanodiamond

期刊

CHEMICAL COMMUNICATIONS
卷 51, 期 44, 页码 9145-9148

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00588d

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资金

  1. Foundation from MOST [2011CBA00504]
  2. NSFC of China [21133010, 21103203, 51221264, 21261160487, 21473223, 21203215]
  3. Strategic Priority Research Program of the Chinese Academy of Sciences [XDA09030103]

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For the first time, we give a fundamental understanding of the effect of borate-modified nanodiamond on propane oxidative dehydrogenation reaction. Upon increasing the loading amount of borate on the carbon surface, the propene selectivity shows a volcanic curve. The adsorption sites of borate at different loading amounts are thoroughly considered.

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