期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 43, 页码 9002-9005出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02902c
关键词
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资金
- European Research Council under the FP7 framework [ERC 246837]
- Israel Science Foundation
- Kimmel Center for Molecular Design
- Okinawa Institute of Science and Technology
Reported here is the catalytic, acceptorless coupling of alcohols with in situ generated, non-stabilized phosphonium ylides to form olefins as major products. The reaction uses low catalyst loadings and does not require added oxidants. Hydrogenation of the product is minimized and the reaction leads to Z (aliphatic) or E (benzylic) stereospecificity.
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