期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 87, 页码 15804-15807出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc06910f
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资金
- Laboratory Directed Research and Development (LDRD) program at Sandia National Laboratories [LDRD 151300]
- U.S. National Science Foundation (NSF) [CHE-1265608]
- United States Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000]
- NSF [CHE-1039436, CHE-1126265]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1265608] Funding Source: National Science Foundation
Reaction of [kappa(2)-PR2C(SiMe3)Py](2)Zn (R = Ph, 2a; Pr-i, 2b) with CO2 affords the products of formal insertion at the C-Si bond, [kappa(2)-PR2CC(O)O(SiMe3)Py](2)Zn (R = Ph, 3a; Pr-i, 3b). Insertion product 3b was structurally characterized. The reaction appears to be a stepwise insertion and rearrangement of CO2 based on kinetic data.
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